Colomban P. (ed.) Proton Conductors. Solids, membranes and gels - materials and devices. (Chemistry of Solid State Materials 2)

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размер 4.1 МБ
добавлен 12 сентября 2011 г.

Cambridge University Press. 1992. 614 p.

Hydrogen Bond and Protonic Species

The hydrogen bond and chemical parameters favouring proton mobility in solids
Protonic species and their structures
Proton conductors: classification and conductivity
Defects, non-stoichiometry and phase transitions
Structural studies of proton conductors
Hydrogen in metals: structure, diffusion and tunneling

Materials: Preparation, Structures and Properties

Structure and characterization of hydrogen insertion compounds of metal oxides
High temperature proton conductors based on perovskite-type oxides
Highly ionic hydroxides: unexpected proton conductivity in Mg(OH)2 and homologues
Ice
Anhydrous materials: oxonium perchlorate, acid phosphates, arsenates, sulphates and selenates
Hydrogen behaviour in graphite-nitric acid intercalation compounds

Inorganic ion exchangers

Proton-containing beta- and beta''-alumina structure type compounds
Proton conduction in zeolites
Proton containing

Layer hydrates

Phosphates and phosphonates of tetravalent metals as protonic conductors
Hydrogen uranyl phosphate, H₃OUO₂PO₄ 3H₂O (HUP), and related materials
From crystalline to amorphous (particle) hydrates: inorganic polymers, glasses, clays, gels and porous media
Perfluorinates membranes
Mixed inorganic-organic systems: the acid/polymer blends

Proton Dynamics and Charge Transport

Incoherent neutron scattering studies of proton conductors: from the anhydrous solid state to aqueous solutions
NMR studies of local motions in fast protonic conductors
Vibrational spectroscopy of proton conductors
Raman spectroscopic studies of proton conductors
Frequency dependent conductivity, microwave dielectric relaxation and proton dynamics
Measuring the true proton conductivity
D.c. techniques and a.c./d.c. combination techniques
NMR in gels and porous media

Proton Diffusion Mechanisms

Mobility in hydrogen-containing oxide bronzes: the atomic-level detail
Conductivity mechanisms and models in anhydrous protonic conductors
Conduction mechanisms in materials with volatile molecules

Devices

Energy storage and production

Applications of perfluorinated proton conductors (Nafions)
Synthesis of polycrystalline H₃O⁺ and NH₄⁺-beta''/beta-Al₂O₃ and potential applications in steam-electrolysis/fuel-cells
Fuel-cells, steam-electrolysis for hydrogen production and hydrogen separation using high temperature protonic conductors

Small components and microionic devices

Ice-based devices
Solid-state gas sensors operating at room temperature
All solid-state protonic batteries
Applications of proton conductors in electrochromic devices (ECDs)
Supercapacitors and interfacial charge accumulation devices

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