Voloshin Ya.Z., Kostromina N.A., Kraemer R. Clathrochelates. Synthesis, Structure and Properties

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размер 18.21 МБ
добавлен 26 августа 2011 г.

Elsevier. 2002. 433 p.

Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.

Contents

Fundamental concepts of complexes with encapsulated metal ions
Synthesis of clathrochelates
Spatial and electronic structure of clathrochelates
Kinetics and mechanism of synthesis and decomposition of clathrochelates
Properties of clathrochelates
Application possibilities of clathrochelate chemistry
New types of clathrochelates: perspectives of synthesis

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