Wiley-VCH, 2010. - 475 p.
Книга (на английском языке) является четвертым томом серии "Зеленые растворители" и посвящена свойствам веществ, находящихся в критическом и закритическом состоянии, а также особенностям химических реакций и процессов, протекающих в данных условиях. Подробно освещаются расчеты физических свойств, жидкофазные синтезы органических веществ и фотохимические реакции в закритических условиях, гетерогенный и ферментативный катализ, производство наноматериалов, а также межфазный и кислотный катализ.
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Note: Green solvents are environmentally friendly solvents or biosolvents, which are derived from the processing of agricultural crops.
The use of petrochemical solvents are the key to the majority of chemical processes but not without severe implications on the environment. The Montreal Protocol identified the need to re-evaluate chemical processes with regard to their use of volatile organic compounds of VOCs and the impact theses VOCs has on the environment. Green solvents were developed as a more environmentally friendly alteative to petrochemical solvents.
Contents
Introduction
Philip Jessop and Walter Leitner
High-pressure Methods and Equipment
Nils Theyssen, Katherine Scovell, and Martyn Poliakoff
Basic Physical Properties, Phase Behavior and Solubility
Neil R. Foster, Frank P. Lucien, and Raffaella Mammucari
Expanded Liquid Phases in Catalysis: Gas-expanded Liquids and Liquid–Supercritical Fluid Biphasic Systems
Ulrich Hintermair, Walter Leitner, and Philip Jessop
Synthetic Organic Chemistry in Supercritical Fluids
Christopher M. Rayner, Paul M. Rose, and Douglas C. Baes
Heterogeneous Catalysis
Roger Gl?ser
Enzymatic Catalysis
Pedro Lozano, Teresa De Diego, and Jos? L. Iborra
Polymerization in Supercritical Carbon Dioxide
Uwe Beginn
Synthesis of Nanomaterials
Zhimin Liu and Buxing Han
Photochemical and Photo-induced Reactions in Supercritical Fluid Solvents
James M. Tanko
Electrochemical Reactions
Patricia Ann Mabrouk
Coupling Reactions and Separation in Tunable Fluids: Phase Transfer-Catalysis and Acid-catalyzed Reactions
Pamela Pollet, Jason P. Hallett, Charles A. Eckert, and Charles L. Liotta
Chemistry in Near- and Supercritical Water
Andrea Kruse and G. Herbert Vogel
Книга (на английском языке) является четвертым томом серии "Зеленые растворители" и посвящена свойствам веществ, находящихся в критическом и закритическом состоянии, а также особенностям химических реакций и процессов, протекающих в данных условиях. Подробно освещаются расчеты физических свойств, жидкофазные синтезы органических веществ и фотохимические реакции в закритических условиях, гетерогенный и ферментативный катализ, производство наноматериалов, а также межфазный и кислотный катализ.
=====================
Note: Green solvents are environmentally friendly solvents or biosolvents, which are derived from the processing of agricultural crops.
The use of petrochemical solvents are the key to the majority of chemical processes but not without severe implications on the environment. The Montreal Protocol identified the need to re-evaluate chemical processes with regard to their use of volatile organic compounds of VOCs and the impact theses VOCs has on the environment. Green solvents were developed as a more environmentally friendly alteative to petrochemical solvents.
Contents
Introduction
Philip Jessop and Walter Leitner
High-pressure Methods and Equipment
Nils Theyssen, Katherine Scovell, and Martyn Poliakoff
Basic Physical Properties, Phase Behavior and Solubility
Neil R. Foster, Frank P. Lucien, and Raffaella Mammucari
Expanded Liquid Phases in Catalysis: Gas-expanded Liquids and Liquid–Supercritical Fluid Biphasic Systems
Ulrich Hintermair, Walter Leitner, and Philip Jessop
Synthetic Organic Chemistry in Supercritical Fluids
Christopher M. Rayner, Paul M. Rose, and Douglas C. Baes
Heterogeneous Catalysis
Roger Gl?ser
Enzymatic Catalysis
Pedro Lozano, Teresa De Diego, and Jos? L. Iborra
Polymerization in Supercritical Carbon Dioxide
Uwe Beginn
Synthesis of Nanomaterials
Zhimin Liu and Buxing Han
Photochemical and Photo-induced Reactions in Supercritical Fluid Solvents
James M. Tanko
Electrochemical Reactions
Patricia Ann Mabrouk
Coupling Reactions and Separation in Tunable Fluids: Phase Transfer-Catalysis and Acid-catalyzed Reactions
Pamela Pollet, Jason P. Hallett, Charles A. Eckert, and Charles L. Liotta
Chemistry in Near- and Supercritical Water
Andrea Kruse and G. Herbert Vogel