2nd ed. , extended and updated - Published by John Wiley & Sons,
2009. - 868 p.
The chemistry of superacids, that is, of acid systems stronger than
conventional strong mineral Br?nsted acids such as sulfuric acid or
Lewis acids like aluminum trichloride, has developed in the last
two decades into a field of growing interest and importance. It was
J. B. Conant who in 1927 gave the name superacids to acids that
were capable of protonating certain weak bases such as carbonyl
compounds and called attention to acid systems stronger than
conventional mineral acids. The realization that Friedel–Crafts
reactions are, in general, acid catalyzedwith conjugate
Lewis–Br?nsted acid systems frequently acting as the de facto
catalysts extended the scope of acid catalyzed reactions.
General Aspects
Superacid Systems
Carbocations in Superacid Systems
Heterocations in Superacid Systems
Superacid-Catalyzed Reactions
Olah George A., Surya Prakash G.K., Moln?r ?rp?d, Sommer Jean. Superacid chemistry
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