
Environmental Encyclopedia 3
Environmental chemistry
as humic substances, which can stain the water a tea-like
color. Typical concentrations of major ions in fresh water
are: calcium 15 mg/l, sulfate 11 mg/l, chloride 7 mg/l, silica
7 mg/l, sodium 6 mg/l, magnesium 4 mg/l, and potassium
3 mg/l.
The water of clean precipitation is considerably more
dilute than that of surface waters such as lakes. For example,
precipitation at a remote place in Nova Scotia contained 1.6
mg/l of sulfate, 1.3 mg/l chloride, 0.8 mg/l sodium, 0.7 mg/
l nitrate, 0.13 mg/l calcium, 0.08 mg/l ammonium, 0.08
mg/l magnesium, and 0.08 mg/l potassium. Because that
site is about 31 mi (50 km) from the Atlantic Ocean, its
precipitation is influenced by sodium and chloride originat-
ing with sea spray. In comparison, a more central location
in North America had a sodium concentration of 0.09 mg/
l and chloride 0.15 mg/l.
Pollution of surface waters is most often associated
with the dumping of human or industrial sewage, nutrient
inputs from agriculture,
acidification
caused by acidic pre-
cipitation or by acid-mine
drainage
, and industrial inputs
of toxic chemicals. Eutrophication is caused when nutrient
inputs cause large increases in aquatic productivity, especially
in fresh waters and shallow marine waters into which sewage
is dumped or that receive
runoff
containing agricultural
fertilizers. In general, marine ecosystems become eutrophic
when they are fertilized with nitrate, and freshwater systems
with phosphate. Only 35–100 g/l or more of phosphate is
enough to significantly increase the productivity of most
shallow lakes, compared with the background concentration
of about 10 g/l or less.
Freshwater ecosystems can become acidified by receiv-
ing drainage from bogs, by the deposition of acidifying sub-
stances from the atmosphere (such as acidic rain), and by
acid-mine drainage. Atmospheric depositions have caused a
widespread acidification of surface waters in eastern North
America, Scandinavia, and other places. Surface waters acidi-
fied by atmospheric depositions commonly develop pHs of
about 4.5–5.5. Tens of thousands of lake and running-water
ecosystems have been damaged in this way. Acidification
has many biological consequences, including toxicity caused
to many
species
of plants and animals, including fish.
Some industries emit metals to the environment, and
these may pollute fresh and marine waters. For instance,
lakes near large smelters at
Sudbury, Ontario
, have been
polluted by sulfuric
acid
, copper, nickel, and other metals,
which in some cases occur in concentrations large enough
to cause toxicity to aquatic plants and animals.
Mercury contamination of fish is also a significant
problem in many aquatic environments. This phenomenon
is significant in almost all large fish and
sharks
, which
accumulate mercury progressively during their lives and com-
monly have residues in their flesh that exceed 0.5 ppm (this
473
is the criterion set by the World Health Organization for
the maximum concentration of mercury in fish intended for
human consumption). It is likely, however, that the oceanic
mercury is natural in origin, and not associated with human
activities. Many fresh-water fish also develop high concen-
trations of mercury in their flesh, also commonly exceeding
the 0.5 ppm criterion. This phenomenon has been demon-
strated in many remote lakes. The source of mercury may
be mostly natural, or it may originate with industrial sources
whose emissions are transported over a long distance in the
atmosphere before they are deposited to the surface. Severe
mercury pollution has also occurred near certain factories,
such as chlor-alkali plants and pulp mills. The most famous
example occurred at Minamata, Japan, where industrial dis-
charges led to the pollution of marine organisms, and then
resulted in the
poisoning
of fish-eating animals and people.
Environmental chemistry of soil and rocks
The most abundant elements in typical soils and rocks
are oxygen (47%), silicon (28%),
aluminum
(8%), and iron
(3–4%). Virtually all of the other stable elements are also
present in soil and rocks, and all of these can occur in a
great variety of molecular forms and minerals. Under certain
circumstances, some of these chemicals can occur in relatively
high concentrations, sometimes causing ecological damages.
This can occur naturally, as in the case of soils influ-
enced by so-called serpentine minerals, which can contain
hundreds to thousands of ppm of nickel. In addition, indus-
trial emissions of metals from smelters have caused severe
pollution. Soils near Sudbury, for example, can contain nickel
and copper concentrations up to 5,000 ppm each. Even
urban environments can be severely contaminated by certain
metals. Soils collected near urban factories for
recycling
old
automobile
batteries can contain lead in concentrations in
the percent range, while the edges of roads can contain
thousands of ppm of lead emitted through the use of leaded
gasoline
.
Trace toxics
Some chemicals occur in minute concentrations in
water and other components of the environment, yet still
manage to cause significant damages. These chemicals are
sometimes referred to as trace toxics. The best examples are
the numerous compounds known as halogenated hydrocar-
bons, particularly
chlorinated hydrocarbons
such as the
insecticides DDT, DDD, and dieldrin, the dielectric fluids
PCBs, and the chlorinated dioxin, TCDD. These chemicals
are not easily degraded by either
ultraviolet radiation
or
by metabolic reactions, so they are persistent in the environ-
ment. In addition, chlorinated hydrocarbons are virtually
insoluble in water, but are highly soluble in lipids such as
fats and oils. Because most lipids in ecosystems occur within
the bodies of organisms, chlorinated hydrocarbons have a
marked tendency to bioaccumulate (i.e., to occur preferen-