124 Fuels and Lubes: Chemistry and Treatment
medium-speed engine system oils
Lubricating medium-speed trunk piston engines is considered much more
of an exact science than lubricating low-speed crosshead engine cylinders.
Sulphurous by-products from the combustion of high-sulphur fuel are coun-
tered by increasing the amount of over-based additives in the formulation to
give an oil of higher alkalinity, as measured by TBN. But this is not quite as
simple as merely adding alkaline additives. Research is carried out to estab-
lish a balanced blend of the many functionally different additives, for example,
anti-oxidants, anti-wear agents, corrosion inhibitors, detergents, dispersants,
anti-foam agents and pour-point depressants.
The performance of a lubricating oil in a marine medium-speed engine
tends to be measured in terms of its ability to maintain an acceptable level of
TBN in service. TBN retention is influenced by factors such as fuel sulphur
content, combustion quality, lubricating oil make-up, piston ring blow-by and
water contamination. With regard to the oil itself, however, retention is directly
related to additive balance and the quality of the additives used.
Although marine lubricants will continue to rely largely on the types of
additives that have ensured success so far, formulators suggest that more
sophisticated and effective versions can be expected. The search for more pow-
erful synergisms between additives of different species will intensify, and lube
oils that can outlast the life of an engine could be possible in the future.
LineR LaCQueRing
In recent years a number of highly rated medium-speed engines of certain types
have experienced problems with lacquer formation on cylinder liners. This
build-up of lacquer in the honing grooves can result in a smoothed or glazed
liner surface that leads to a significant increase in the rate of oil consumption.
If left unchecked, lacquering can also be accompanied by hard carbonaceous
deposits, which lead to scoring or polishing of the liners and increased engine
operating costs.
A number of common factors link examples of engines in which liner lac-
quering has been found: large variations in load (e.g. frequent and long periods
of idle followed by full load operation); high mean effective pressure medium-
speed designs; and low-sulphur, mainly distillate, fuels. Lacquering can typi-
cally occur in the propulsion engines of offshore supply vessels and short-sea
ships. Lacquer characteristically contains both organic and inorganic (metal
salts) materials, the colour varies from very light amber to dark brown, and
there is uneven distribution over the liner.
Modern, highly rated engines exploit much higher fuel-injection pressures
and shorter injection times. The total injection, ignition and combustion proc-
ess has to take place in a few degrees of crank angle under conditions in which,
besides complete combustion, thermal cracking of fuel components can be
expected. If these cracked components reach the relatively cool cylinder liner sur-
face, they will condense, concentrate and start the formation of resinous lacquer
by a process of polymerization and evaporation of the light ends (see Figure 4.7).