362 Individual Flavors and Colorants
Essential Oil
The aerial part of the plant consisting of the leaves and fl owering tops represents the
herb from which spearmint essential oil can be steam - distilled. On an average, the
yield of oil is 0.6%. The oil is colorless, yellow, or greenish - yellow with a character-
istic appealing aroma and fl avor, which is believed to improve with age (Prakash
1990 ). The aroma is described as fresh, penetrating, minty, sharp, but pleasantly aro-
matic with a touch of herbaceous note.
The main constituent is l - carvone, which is also present in caraway oil and dill oil.
Unlike Japanese mint, spearmint does not have a large percentage of menthol. Chemical
studies of a sample from Bangladesh show 73.29% carvone, 7.59% d - limonene, and
3.83% dihydrocarvone (Chowdhury et al . 2007 ). Similarly, an analysis of Scotch
spearmint oil shows 69.3% and 66.7% of l - carvone in two varieties (Liu et al. 2005 ).
Limonene is also noted in substantial quantities. In a sample from Iran, among the 28
components noted, carvone is present only to the extent of 22.40%; linalool (11.25%)
and limonene (10.80%) are also noticed (Hadjiakhoondi et al. 2000 ). In a Chinese
study, carvone is not seen as a main component (Xu et al. 2003 ). The principal com-
ponents among 39 are piperitenone oxide, 1,8 - cineole, dl - limonene, β - myrcene, and
β - pinene. However, Chen et al. (2003) in another Chinese study found carvone, limo-
nene, and dihydrocarvone as the main constituents.
Lawrence (2008) has reviewed the analytical data of a large number of studies from
all over the world. His own data from the United States show that the carvone content
is between 58.47% and 69.44%. To study in detail many minor components present,
the reader is referred to the review.
The FCC describes spearmint oil as a colorless, yellow, or green - yellow liquid
having the characteristic odor and taste of spearmint.
Physical characteristics as defi ned by the FCC are as follows.
Optical rotation − 48 ° to − 5 °
Refractive index 1.484 – 1.491 at 20 ° C
Specifi c gravity 0.917 – 0.934
Solubility 1 mL dissolves in 1 mL of 80% alcohol
Oleoresin is not generally made in the case of spearmint. However, FEMA and
CAS numbers have been allotted to the extract, indicative of its production. Some
fl avonoids and phenolic compounds including rosmarinic acid have also been reported
(Zheng et al. 2006 ).
Uses
Spearmint oil is a valuable fl avoring material for chewing gum, confectionery, baked
sweet foods, desserts, jellies, and a variety of other sweet items. Mint - fl avored chewy
and hard candies are extremely popular.
Spearmint oil is one of the most widely used fl avors for toothpaste because of its
effective mouth - freshening qualities. For the same reason, it is used in mouthwashes
and dental preparations.