
Corrosion and Scaling 
1335 
2. 
This results in high  concentrations  of  zincate  ions that are effective 
scavengers. However, high concentrations  of  zincate can lead to problems 
related  to mud performance. 
The second type  of  zinc-base  scavenger, utilizes  highly  water-soluble, 
organic, zinc-chelate compounds.  The metal ions are bonded with organic 
compounds, forming "metal chelates" that are highly soluble in water. This 
high  solubility  enables  their  use  in  clear  drilling  fluids; whereas,  a less- 
soluble  scavenger can  settle out and become ineffective. Another  advan- 
tage  of  using  zinc  chelates  is  that  they  are effective  over  a  wide  range 
of 
pH. 
IfOmB8Se 
SC8VengerS. 
There is only one iron compound that is commercially 
available as a sulfide scavenger for drilling fluids. The product  is  a synthetic, 
high-surface-area magnetite,  Fe,O,.  Fe,O,  is often used in low-pH muds, where 
sulfides in the mud exist largely as acidic molecular 
H,S. 
This is because  reac- 
tions 
of 
Fe,O,  in normal alkaline-mud  pH ranges  proceed  at 
a 
slow  rate. 
Consequently, a soluble sulfide may  coexist with unreacted Fe,O,  for undesirably 
long periods of time. The scavenging reaction of 
H,S 
by  Fe,O,  proceeds accord- 
ing to the following equation  by  type 
A 
reaction: 
Fe90, 
+ 
6H,S 
+ 
3FeS, 
5 
+ 
4H,O 
+ 
2H, 
t 
The reaction efficiency and products formed depend on downhole variables. 
The most important variables are pH, temperature, reaction time, post-reaction 
aging time, and mud-shear conditions, An advantage of using Fe,O,  over other 
chemicals  is  that large quantities  of  insoluble  material  can  be added without 
affecting the drilling fluid properties. Under optimum conditions with adequate 
Fe,O,  surface area exposed, the product may remove up 
to 
2,000 
mg/L  sulfides 
for 
1 
lbm/bbl 
(2.85 
kg/m3) Fe,O,  treatment.  Fe,O,  is often used  as a pretreat- 
ment to reduce the threat to drilling tools 
and 
health of the drilling crew, which 
may  result  from a  kick  of  gas  containing high  H,S  content.  Although  the 
chemical composition is the same as magnetite,  Fe,O,,  it is  not very magnetic 
and, therefore,  does not cling to drillpipe or casing. 
Microbiocides. 
There are several  microbiocides  available commercially  that 
can  perform an  effective  function  in controlling  microbial  activity. Some 
of 
these  chemicals 
are 
inorganic, such as chlorine,  sodium hypochlorite,  calcium 
hypochlorite,  hydrogen  peroxide,  chromates  and compounds  of  mercury  and 
silver.  However, the organic chemicals find 
the 
highest  use  as microbiocides. 
Some examples 
of 
these organic compounds  are peracetic  acid, paraformalde- 
hyde,  polychlorophenols  and quaternary ammonium derivatives, 
to 
name  a 
few 
[208]. 
Microbiocides may  be  toxic to humans; therefore,  care  must be  taken when 
used. When selecting the microbiocide,  the field engineer can obtain pertinent 
information  on chemicals from the service  company providing  the  chemicals. 
The microbiocide  selected  must  be compatible with  the system in which  it is 
being used. Some chemicals such as quaternary amines have dual functions; one 
as microbiocides and the other as film-forming corrosion inhibitors. Insufficient 
concentrations 
of 
this 
type 
of chemical may  not be enough 
to 
coat the whole 
surface of metal and can cause pitting corrosion. The selection must also depend 
on chemicals that can produce the desired control in minimum time limits 
and