9.8 Notes and References 603
and it is not necessary for basaltic magma, where the viscosity is sufficiently low
that cracks can propagate at sufficient speed that freezing does not occur.
The problem particularly arises for granitic plutons, where huge batholiths have
been emplaced in the continental crust. The viscosity of rhyolite is much higher
than that of basalt, so that fractures would have to be much larger, ascent times
would be greater, and freezing more likely. Despite this, ascent via fracture has
been suggested (Clemens and Mawer 1992; Petford et al. 1994). On the other hand,
because the ascent distance d
s
depends on the cube of the size, 10 km diapirs could
rise 20–30 times their own size, and thus to the surface. Smaller diapirs would not
do so well, though.
Against the idea of large diapir ascent may be the choice of viscosity. The value
η
r
= 10
18
Pa s is a typical asthenospheric sort of value, perhaps associated with
basalts at 1,500 K. But the melting point of granites is much lower, perhaps around
1,000 K, which is suggestive of higher values of η
r
. If this were the case, it would
virtually rule out diapiric uprise via rind softening. An alternative possibility is that
alluded to above in passing, the analogy with regelation. Regelation refers to the
passage of a heavy object through a block of ice. Because increased pressure lowers
the melting point of ice, a thin layer of water forms below the object and is squirted
round by the pressure gradient to the rear, where it refreezes, thus enabling passage
of the solid through the ice (Nye 1967). The analogy here is not quite the same,
however. If a layer of hot basalt is ponded at the base of the continental crust, it
will melt the crust, forming a light silicic magma which floats on top of the basalt.
As the basalt cools, crystals will begin to grow at the interface with the rhyolite. As
the crystals continue to grow, they will most likely form a mush or slurry, and will
cause the interstitial liquid to become increasingly silicic. Eventually, the heavy mat
of crystals will become unstable and sink to the floor (or this may occur continu-
ously). Apparently this will continue until the temperature decreases to the (cotectic)
point where also the rhyolite is crystallising. From this point the upper silicic layer
is also being removed, and the whole system effectively moves upwards at a rate
controlled by recrystallisation, and creep of the country rock need not be involved.
In the process, the magma presumably becomes granitic through the incorporation
of the crustal rocks. The idea is essentially due to Huppert and Sparks (1988).
Alloy Solidification There are a number of books and proceedings volumes
on solidification in multi-component systems. Amongst these, one should mention
Flemings (1974), Kurz and Fisher (1998), Davis et al. (1992), Ehrhard et al. (2001)
and Loper (1987), the last three of which provide multidisciplinary comparisons be-
tween different fields. Much of the interest originated from the study of the forma-
tion of metal alloy castings in metallurgy, particularly the formation of the defects
known as ‘freckles’. Early on it was found that an experimentally viable analogue
to the industrially important alloys such as lead–tin was the aqueous ammonium
chloride solution. The group led by Herbert Huppert at Cambridge has pioneered
the exploration of this and other aqueous solutions in freezing conditions, and Hup-
pert in particular, together with his colleague Steve Sparks, has uncovered, or per-
haps created, a gold mine of experimentally driven insights into all sorts of geolog-
ical processes in magma chambers; see, for example, Huppert (1986, 1990, 2000).