
15.1 
Forms of Atmospheric 
Energy 
493 
juxtaposed horizontally (Fig.  15.3). Hydrostatic equilibrium implies a pressure 
gradient force  directed from the heavier fluid to the lighter one. Motion will 
then develop internally to alleviate the mechanical imbalance. The nonrotating 
system in Fig.  15.3 accomplishes this by rearranging mass so that heavier fluid 
undercuts and eventually comes to rest underneath lighter fluid, so the system's 
final  state  is  hydrostatically  stable.  By  lowering  the  center  of gravity  of the 
system, this process releases potential energy, which is converted  into kinetic 
energy and eventually dissipated by viscosity to increase the system's internal 
energy. 
In  the  atmosphere,  horizontal  rearrangement  of mass  is  inhibited  by  ro- 
tation,  which  deflects  air  motion  parallel  to  isobars  (e.g.,  into  the  page  in 
Fig.  15.3).  Nevertheless,  the  pressure  gradient  along  0  surfaces  enables  air 
motion to develop and, although more complex, to neutralize the mechanical 
imbalance.  The  Coriolis  force  makes  those  motions  highly rotational,  which 
favors  horizontal  mixing  (Fig.  12.4).  This  process  is  illustrated  by  interleav- 
ing  swirls  of tropical  and  polar  air  in  the  cyclone  off the  coast  of Africa  in 
Fig.  1.15. By  mixing  air  horizontally,  extratropical  cyclones  homogenize  the 
distribution  of mass  along isentropic  surfaces, which  drives  isobaric  surfaces 
back into coincidence with isentropic surfaces and restores the thermal struc- 
ture to barotropic  stratification.  Those  motions  also result in a  net poleward 
transfer of heat and moisture because air drawn poleward from low latitudes 
has  greater  moist  static  energy  than  air  drawn  equatorward  from  high  lati- 
tudes.  In making the horizontal  mass distribution uniform, air motions lower 
the overall center of gravity of the atmosphere.  Potential  energy is therefore 
converted into kinetic energy, which in turn is dissipated by viscosity, converted 
into internal energy, and finally rejected to space as heat. 
Air  motions  responsible  for  this  redistribution  of  mass  are  fueled  by  a 
conversion  of potential  energy to kinetic  energy. They  are  termed 
baroclinic 
instability 
because their source of energy is directly related to the baroclinicity 
of  the  stratification.  Since  temperature  then  varies  along  isobaric  surfaces, 
thermal wind balance  implies that  those  motions  are  also  related  to vertical 
shear of the flow. 
ADIABATIC ADJUSTMENT 
The potential energy available for conversion to kinetic energy is reflected 
in  the  departure  from  barotropic  stratification.  Consider  an  adiabatic  redis- 
tribution of mass from a given baroclinic state. Because air must move along 
0 surfaces, horizontal  mixing will  eventually render the distributions  of mass 
and pressure  uniform over those  surfaces,  restoring  the thermal structure  to 
barotropic  stratification.  In  that  limiting  state,  the  atmosphere  has no  more 
potential energy available for conversion, so ~  =  ~min. 
The 
available potential energy d 
(Lorenz,  1955) is defined as the difference 
between the total potential  energy for the state under consideration  and the