
206 8- STOCK PREPARATION AND ADDITIVES FOR PAPERMAKING
dye at the oxygen and nitrogen atoms through
formation of coordinate bonds. Actually alum is
a common mordant used in textile dyeing. In pulp
and paper literature the alum rosin complex is
depicted in terms of ionic interactions (which must
form exceedingly hydrophilic linkages). In fact
coordinate structures are formed that are nonpolar
and hydrophobic in nature, although ionic interac-
tions are important for retention.
In a series of experiments Subrahmanyam and
Biermann (1992) showed unequivocally that
coordination chemistry is central to how alum
achieves its function in rosin sizing. Rosin sizing
with numerous highly coordinating transition and
lanthanide elements was efficacious at a variety of
acid and alkaline pH's depending on the formation
constant with hydroxide of each individual ele-
ment. Formation constants with rosinate, sulfate,
chloride, and other ligands were also relevant to
the degree of sizing.
Aluminum ions in solution form polymers by
sharing hydroxide groups. Two adjacent alumi-
num ions share two hydroxide groups to form the
chain; these linkages are termed hydroxo linkages
and are relatively nonpolar linkages, unlike the
polar linkages often shown that would be
destroyed by water. The chemistry of aluminum
is developed in more detail in Section 14.7.
The results of the first study allowed
Biermann (1992) to take rosin sizing to a pH of 10
using polyamines with very high charge densities.
This indicates that alkaline rosin sizing is possible,
something that used to be debated.
8.7 ANNOTATED BIBLIOGRAPHY
Auxiliary equipment
1.
Ingraham, H.G. and E.E. Forslind, Auxiliary
apparatus and operations preliminary to paper
machines, in Pulp and Paper Manufacture,
Volume3,
MacDonald, R.G., Ed., McGraw-
Hill, New York, 1969, pp 185-243. This is
a good description of equipment and opera-
tion of vacuum systems, stock chests, white
water flow with material balance, savealls,
centrifugal separators, deculators, and
screens.
2.
TAPPITIS 0410-01 gives fan pump calcula-
tions.
3.
Gooding, R.W. and Craig, D.F., The effect
of slot spacing on pulp screen capacity, Tappi
J. 75(2):71-75(1992). Blinding, accumula-
tion of fibers near the screen plate apertures,
occurs when more than 7% of the fibers are
longer than the slot spacing. When 30% of
the fibers are of this length severe blinding
may occur, decreasing the capacity of the
screens appreciably.
Fillers
4.
Schwalbe, H.C., Fillers and loading, in Pulp
and Paper Science and Technology, Volume
2,
Libby, C.E., Ed. McGraw-Hill, New
York, 1962, pp 60-89. This is a good over-
view on the physical properties of fillers.
Zeta potential
The zeta potential is a colloidal effect having
to do with charge distributions on the surface of
suspended particles. The zeta potential is the
charge density on the surface of colloids and
suspended particles. It varies from about -50 mV
to + 50 mV. Retention is often at a maximum
when the charge density is near zero. This is
probably where the solubility is lowest. At one
time,
it was thought to be the panacea for wet end
control. While not meeting this expectation, it
does have some use for wet end control. Wet end
reactions such as retention are looked at primarily
from the point of view of charge distributions. As
discussed in several sections of this book, howev-
er, this is only part of the picture.
5.
TAPPI TIS 0106-05 (1988) gives trade
names, % solids, brightness, and median
particle sizes on a variety of North American
calcium carbonates from various suppliers.
TAPPI TIS 0106-06 (1988) does this for
kaolin clays, and TAPPI TIS 0106-07 (1989)
does this for titanium dioxide.
Internal
sizing—general
aspects,
6. Reynolds, W.F., Ed., The Sizing of Paper,
2nd ed., TAPPI, Atlanta, 1989. 156 p. This
is a good overview of internal sizing with
rosin,^ AKD, ASA, stearic acid, and
fluorochemicals. Surface sizing and testing
of paper and board for sizing are also cov-
ered. The volume is fairly general.