
Environmental Encyclopedia 3
Solidification of hazardous materials
vendors of S/S services in the United States, and though the
details of some processes are privileged, many fundamental
aspects are widely known and practiced by the companies.
S/S technologies try to decrease the solubility, the
exposed surface area, and/or the toxicity of a
hazardous
material
. While the methods also make wastes easier to
handle, there are some disadvantages. Certain wastes are not
good candidates for S/S. For example, a number of inorganic
and organic substances interfere with the way that S/S addi-
tives will perform, resulting in weaker, less durable, more
permeable
solids or blocks. Another disadvantage is that
S/S often double the volume and weight of a waste material,
which may greatly affect
transportation
and final disposal
costs (not considering potential costs associated with un-
treated materials contaminating the
environment
). S/S ad-
ditives, such as encapsulators, are available that will not
increase the weight and volume of the wastes so dramatically,
but these additives tend to be more expensive and difficult
to use.
Methods for S/S are characterized by binders, reaction
types, and processing schemes. Binders may be inorganic or
organic substances. Examples of inorganic binders which are
often used in various combinations include cements, lime,
pozzolans, which react with lime and moisture to form a
cement such as
fly ash
, and silicates. Among the organic
types generally used are epoxies, polyesters, asphalt, and
polyolefins (e.g. polyethylene). Organic binders have also
been mixed with inorganic types, e.g., polyurethane and
cement. The performance of a binder system for a given
waste is evaluated on a case-by-case basis; however, much
has been learned in recent years about the compatibility and
performance of binders with certain wastes, which allows
for some intelligent initial decisions related to binder selec-
tion and processing requirements.
Among the types of reactions used to characterize S/
S are
sorption
, pozzolan, pozzolan-portland cement, and
thermoplastic microencapsulation. Sorption refers to the ad-
dition of a solid to sorb free liquid in a waste. Activated
carbon
, gypsum, and clays have been used in this capacity.
Pozzolan reactions typically involve adding fly ash, lime, and
perhaps water to a waste. The mixture of fly ash, lime,
and water form a low-strength cement that physically traps
contaminants. This system is very alkaline and therefore may
not be compatible with certain wastes. For example, a waste
containing high amounts of ammonium ions would pose a
problem because, under highly alkaline conditions, the toxic
gas ammonia would be released. Also, sodium borate, carbo-
hydrates, oil, and grease are known to interfere with the
process.
The pozzolan-portland cement process consists of
adding a pozzolan, often fly ash, and a portland cement to
a waste. It may be necessary to add water if enough is not
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present in the waste. The resulting product is a high-strength
matrix that primarily entraps contaminants. The perform-
ance of the system can be enhanced through the use of
silicates to prevent interference by metals, clays to absorb
excessive liquids and certain ions, surfactants to incorporate
organic solvents, and a variety of sorbents that will hold on
to toxicants as the solid matrix forms. Care is needed in
selecting a sorbent because, for example, an acidic sorbent
might dissolve a metal hydroxide, thereby increasing the
mobility of the metal, or result in the release of toxic gases
such as
hydrogen
sulfide or hydrogen cyanide. Borates, oil,
and grease can also interfere with this process.
Thermoplastic encapsulation is accomplished by
blending a waste with materials such as melted asphalt,
polyethylene, or wax. The technique is more difficult and
costly than the other methods introduced above because
specialized equipment and higher temperatures are required.
At these higher temperatures it is possible that certain haz-
ardous materials will violently react. Additionally, it is known
that high salt levels, certain organic solvents, and grease will
interfere with the process.
There are basically four categories of processing
schemes for S/S. For in-drum processing, S/S additives and
waste are mixed and allowed to solidify in a drum. The drum
and its contents are then disposed. In-plant processing is
a second category which refers simply to performing S/S
procedures at an established facility. The facility might have
been designed by a company for their own wastes or as a
S/S plant which serves a number of industries.
A third category is mobile-plant processing, in which
S/S operations are moved from site to site. The fourth cate-
gory is in-situ processing which involves adding S/S additives
directly to a
lagoon
or
contaminated soil
.
As may be inferred from the above discussion, the
goals of S/S operations are to remove free liquids from
a waste, generate a solid matrix that will reliably contain
hazardous materials, and/or create a waste that is no longer
hazardous. The first goal is important because current regu-
lations in the
Resource Conservation and Recovery Act
(RCRA) stipulate that free liquids are not to be disposed of
in a
landfill
. The third goal is obviously important because
disposing of a
hazardous waste
, called delisting, is much
more costly and time-consuming than disposing of a regular
waste.
Wastes are deemed to be hazardous on the basis of
four characteristic tests and a series of listings. The tests
are related to the ignitability, reactivity, corrosiveness, and
extraction procedure (EP) toxicity of the waste. It is possible
that S/S procedures delist a waste in any of the four test
characteristics. The processes may also chemically transform
a substance listed as hazardous waste by the
Environmental
Protection Agency
(EPA) into a non-hazardous chemical.