
matters. Support is often given to scientific initiatives under considera-
tion by national or international agencies that will benefit IAGA science.
For example, a series of IAGA Resolutions supported the initiation of
and extensions to the International Equatorial Electrojet Year (IEEY)
project (1991–1994). The project not only produced good science, but
also resulted in investment in observational facilities at low-latitudes,
benefiting scientists in the less developed world. Although the IEEY
has finished, the impetus it gave to research in the equatorial regions con-
tinues. Similarly, IAGA has supported the Decade of Geopotential
Research, which appears likely to achieve its goal of securing uninter-
rupted geomagnetic field satellite survey measurements spanning a
decade (including the Ørsted and CHAMP missions).
IAGA science is also promoted through collaboration with other
bodies with similar interests. There are links with the other IUGG
Associations and with Inter-Association bodies including Studies of
the Earth ’s Deep Interior (SEDI) (q.v.) and the Working Group on
Electric and Magnetic Studies on Earthquakes and Volcanoes (EMSEV).
There are formal contacts for liaison with the International Lithosphere
Program (ILP), the Scientific Committee on Antarctic Research (SCAR),
the Committee on Space Research (COSPAR), and the Scientific
Committee on Solar Terrestrial Physics (SCOSTEP).
IAGA cooperates with the World Data Center system on the definition
of geomagnetic data exchange formats and management and preservation
of analog and digital databases. The Association has provided strong
support to INTERMAGNET (q.v.), the international program promoting
the modernization of magnetic observatory practice and the distribution
of data in near real time. IAGA advises bodies such as the International
Organization for Standardization (ISO).
IAGA science in the 21st century
IAGA science, because of the pervasiveness of the geomagnetic field
and its interactions with charged particles and electrically conducting
materials, is useful for studies of properties and processes in practi-
cally all parts of the solid Earth, the atmosphere, and the surrounding
space environment. As well as covering a vast range of length scales,
IAGA science covers timescales from seconds to billions of years.
Modern-day observatories record rapid variations during magnetic
storms caused by the interaction of the solar wind with the magneto-
sphere; the imprinting of the paleomagnetic field in rocks provides
records of geodynamic changes on geological timescales.
While IAGA provides an international focus for fundamental research
resulting in advances in understanding in specialist areas, national and
international funding for research often focuses on issues of societal
concern. IAGA science is providing answers to many important ques-
tions, and through its links to other bodies and projects the Association
is able to foster the building of the interdisciplinary teams required to
address complex problems of interest to society.
For instance, a natural goal for IAGA scientists is to be able to
understand and model the whole Sun-Earth system including the com-
plex interactions and feedbacks controlling the transfer of energy
momentum and matter between parts of the system. Research in this
area is proving relevant to the problem of how to disentangle natural
from anthropogenic causes of climate change. This area of science also
underpins the understanding of how “space weather” conditions affect
the risk to technological systems and human activities on the ground
and in space. For example, during magnetic storms, electrical power
distribution grids, radio communications, GPS accuracy, and satellite
operations can be adversely affected. Also in the geohazards area,
EMSEV is charged with establishing firm scientific understanding of
the generation mechanisms of any signals that may help to mitigate
the effects of earthquakes and volcanoes.
IAGA is responsible for the production of the International Geo-
magnetic Reference Field, used in a variety of scientific and “real
world” applications, including navigation, and hydrocarbons explora-
tion and production. The Association is responsible for the definition
of the most widely used magnetic activity indices, and works closely
with the International Service for Geomagnetic Indices, the body
responsible for their production and distribution.
IAGA has a long history, and its science remains vigorous and rele-
vant. Rapid advances in scientific understanding are resulting from
improved instruments, better observations and data analysis techni-
ques, the wealth of satellite data now routinely available, and the
power of modern computer technology. As the 50th anniversary of
the IGY approaches, IAGA is promoting the concept of an “Electronic
Geophysical Year” (eGY), for 2007–2008, taking advantage of the
modern capability to link distributed computing resources to multiple
remote sources of data and modeling codes to address scientific pro-
blems. This initiative is in line with the Association’s mission to
promote international scientific cooperation and collaboration, and has
the potential to advance the ability of scientists in developing countries
to participate in leading-edge research.
(The principal point of contact with the Association is the IAGA
Secretary General, and IAGA communicates with its members and
the public through its Web site and through issues of IAGA News.)
David Kerridge
Bibliography
Naoshi Fukushima, 1995. History of the International Association of
Geomagnetism and Aeronomy (IAGA). IUGG Chronicle, 226:
73–87.
The IAGA Web site: http://www.iugg.org/IAGA/
Cross-references
CHAMP
Chapman, Sydney (1888–1970)
Ørsted
SEDI
IDEAL SOLUTION THEORY
Consider two different substances; mix them together and in general
they will form a solution, like sugar and coffee, for example. We call
solvent the substance present in the largest quantity (coffee), and solute
the other (sugar). In general solutions may have more than one solute,
and/or more than one solvent, but for simplicity we will focus here
only on binary mixtures.
The behavior of solutions can be understood in terms of the chemical
potential m
i
, which represents the constant of proportionality between
the energy of the system and the amount of the specie i (Wannier, 1966):
m
i
¼
]E
]N
i
S;V
(Eq. 1)
where E is the internal energy of the system, S is the entropy , V is the
volume, and N
i
is the number of particles of the specie i. Alternative equiva-
lent definitions of the chemical potential are (Wannier , 1966; Mandl, 1997):
m
i
¼
]F
]N
i
T;V
¼
]G
]N
i
T; p
¼T
]S
]N
i
E;V
(Eq. 2)
where F and G are the Helmholtz and Gibbs free energies of the sys-
tem, T is the temperature, and p is the pressure.
We recall the statistical mechanics definition of the Helmholtz free
energy for a classical system (Frenkel, 1996):
F ¼k
B
T ln
1
L
3N
N!
Z
V
dR
1
...
Z
V
dR
N
e
UðR
1
;...;R
N
;TÞ=k
B
T
; (Eq. 3)
408 IDEAL SOLUTION THEORY