
350 9 Boundary-Value Problems
such that the spatial dependence is described by the inhomogeneous Helmholtz equation
+
2
k
2
Ψ
k
r4ΠΡ
Ω
r (9.167)
where k Ω/c is the wave number. One could, of course, perform a Fourier analysis of
the spatial dependence also, but we prefer to begin with a more traditional partial-wave
expansion of the Green function, which satisfies an equation of the form
+
2
G k
2
G 4Π∆
r
r
'
(9.168)
with boundary conditions to be specified later. Once we have the Green function, the solu-
tion to the original wave equation becomes
Ψ
k
rΦ
k
r
G
k
r,
r
'
Ρ
Ω
r
'
V
'
(9.169)
where Φ
k
is a solution to the homogeneous equation
+
2
k
2
Φ
k
r0 (9.170)
that is determined by matching the boundary conditions.
For example, in the time-independent formalism for scattering by a localized distribu-
tion, one specifies that the asymptotic wave function takes the form of an incident plane
wave plus an outgoing spherical wave of the form
r D r
'
Ψ
k
r Exp
k ,
r f
k
'
,
k
Expk
'
r
r
(9.171)
where the scattering amplitude f is the amplitude of the spherical wave. The incident wave
vector
k
Ω
c
ˆ
k specifies both the frequency Ω and direction
ˆ
k for the incident wave while
the direction of the outgoing wave is specified by
ˆ
k
'
ˆr. The magnitude of the scattered
and incident wave vectors are equal for elastic scattering, such that k
'
k Ω/c,but
differ for inelastic scattering. If we choose the ˆz axis along the incident direction, we may
write the asymptotic wave function for elastic scattering as
r D r
'
Ψ
k
r Expkz f
k
Θ, Φ
Expkr
r
(9.172)
Including the time dependence, the planes of constant phase in the incident component
Φ
r,tExpkz Ωt (9.173)
are clearly seen to travel in the direction of increasing z with phase velocity c. Similarly,
spheres of constant phase in the scattered wave
Ψ
sc
r,t-
Expkr Ωt
r
(9.174)
move radially outward with the same phase velocity. Thus, outgoing boundary conditions
require
r D r
'
G
k
r,
r
'
Expkr
r
(9.175)
However, a more rigorous treatment would represent the incoming wave by a localized
wave packet of finite extent, rather than a plane wave.