
EXAMPLE PROBLEMS 211
∂T
∗
∂r
∗
= 0atr
∗
=
1
√
Fo
t
,t
∗
> 0 (4.E.5-13)
∂T
∗
∂r
∗
=−Bi
t
Fo
t
(1 − T
∗
) at r
∗
= 0,t
∗
> 0 (4.E.5-14)
where Bi
t
≡ hR/k is the thermal Biot number.
Now let us consider how this system of describing equations can be simplified
(step 8). We note that the curvature effects can be ignored when
√
Fo
t
1, cor-
responding to short contact times for which the thermal boundary layer will be
thin in comparison to the radius of the sphere. If
√
Fo
t
1, the boundary con-
dition given by equation (4.E.5-13) can be applied at infinity. A zero conductive
heat flux far from the surface of the sphere implies no change in the temperature
outside the thermal boundary layer. Hence, equation (4.E.5-13) can be replaced
by the condition that T
∗
= 0asr
∗
→∞. Equation (4.E.5-14) indicates that as
Bi
t
→∞,T
∗
→ 1 to ensure that ∂T
∗
/∂r
∗
remains bounded of
◦
(1). This implies
that the surface temperature of the sphere is at T
∞
and that there is essentially no
temperature gradient in the liquid. Hence, for
√
Fo
t
1 and large Biot numbers,
the describing equations simplify to
∂T
∗
∂t
∗
=
∂
2
T
∗
∂r
∗2
(4.E.5-15)
T
∗
= 0att
∗
≤ 0, 0 ≤ r
∗
< ∞ (4.E.5-16)
T
∗
= 0atr
∗
→∞,t
∗
> 0 (4.E.5-17)
T
∗
= 1atr
∗
= 0,t
∗
> 0 (4.E.5-18)
This simplified set of describing equations can be solved via standard methods such
as combination of variables.
4.E.6 Evaporative Cooling of a Liquid Film
An infinitely wide film of an incompressible volatile pure (i.e., single compo-
nent) liquid has an initial thickness of L
0
and is resting on a solid boundary that
is maintained at a constant temperature T
0
. Initially, the entire liquid film is at
this temperature. At time t = 0, evaporation from the film begins that causes the
film thickness to decrease, thus implying that this is a moving boundary prob-
lem. The surrounding gas phase is assumed to transfer negligible heat to the
liquid film. Hence, the latent heat of vaporization (evaporation) must be supplied
entirely by heat conduction from the liquid film. This, of course, causes heat trans-
fer within the liquid film. The evaporative mass flux at the free surface n
G
is
given by
n
G
= k
•
G
p
◦
L
(units of mass/area · time) (4.E.6-1)