Additional factors that can be of local significance in
the thermal history of orogens include magmatic and
strain heating, advective transfer of heat via fluids, and
the heat budget of mineral reactions.
Several means are available to construct P–T paths
in a rock or suite of cogenetic rocks for the terrane
in which they were metamorphosed. Broad paths are
defined by facies series and metamorphic zones.
Thermobarometry on mineral assemblages and zoned
minerals can yield quantitative data but caution must
be exercised because of disequilibrium effects resulting
from sluggish kinetics and overprinting. Further con-
straints are provided by mineral inclusions in poikilo-
blasts and other relic mineral assemblages preserved
in reaction textures; these assemblages can be placed
in petrogenetic grids derived from experimental and
thermodynamic data. High temperatures and complete
mineral equilibration at peak metamorphic conditions
can all but eliminate the prograde path record; for this
reason, retrograde paths are generally more readily
determined.
Chronologic data at specific P–T points in the meta-
morphic path permit construction of a complete P–T–t
path; such information provides quantitative estimates
of rates of mineral growth and of burial and exhuma-
tion during metamorphism.
Orogens and the metamorphic terranes in them are
infinitely variable in detail. Some Mesozoic–Cenozoic
orogens of the circum-Pacific have paired belts with
high P/T metamorphism developed in the accretionary
wedge and intermediate- to low-P metamorphism
farther inland coincident with the magmatic arc. Most
orogens, however, are not so simple because of multi-
ple episodes of docking and suturing of island arcs,
oceanic plateaus, ophiolite, and continental fragments
onto overriding continental plates. Some orogens ex-
perienced culminating continent–continent collisions
and suturing, only to be later affected by crustal exten-
sion and rifting.
The classic Barrovian metamorphic zones devel-
oped in pelitic rocks at intermediate pressures have
been a standard reference for regional metamorphism
in orogens since the work of George Barrow in the
Scottish Highlands a century ago. Successive prograde
appearance via continuous and discontinuous reactions
of chlorite, biotite, garnet, staurolite, kyanite, sillima-
nite, and sillimanite K-feldspar ( migmatite) define
these Barrovian zones. Higher grade minerals and
assemblages of the granulite facies found in other
terranes around the world include cordierite, spinel,
sapphirine, and orthopyroxene K-feldspar in lieu of
biotite.
Widespread metabasites in Barrovian terranes have
fewer phases formed by mostly continuous reactions,
hindering definition of P–T conditions from mineral
assemblages. Greenschist-facies metabasites in chlorite
and biotite pelite zones contain epidote chlorite
actinolite albite quartz calcite titanite
Fe–Ti oxides. In the garnet zone, aluminous horn-
blende replaces actinolite, oligoclase replaces albite,
and almandine-rich garnet may also appear. Chlorite
and epidote disappear in the amphibolite facies (stau-
rolite, kyanite, and sillimanite zones) and pyroxenes
replace hornblende as the dominant mafic phase in the
granulite facies.
Intermediate-P metamorphism defines open-loop,
clockwise P–T paths in orogens where the continental
crust is thickened and thermal relaxation occurs over at
least tens of millions of years. In pelitic rocks, this path
is recorded in prograde kyanite, perhaps preserved as
inclusions in cores of porphyroblasts, followed by later
higher T sillimanite.
Lower P regional metamorphism in some orogens
resembles that developed in contact aureoles sur-
rounding magmatic intrusions except for the concur-
rent deformation that creates tectonite fabric instead
of hornfelsic. Indeed, this Buchan style is sometimes
referred to as regional contact metamorphism because
of widespread more or less synchronous granitoid
intrusions that serve as an important heat source, per-
haps with an additional heat flux from underplating
mantle-derived basaltic magma. The typical flat-loop,
counter-clockwise P–T paths recorded for Buchan
metamorphism reflect this external input of heat. The
lack of much change in P during the prograde and
retrograde paths reflects the lack of concurrent crustal
thickening and consequent isostatic unroofing adjust-
ments. In pelitic rocks, the prograde Buchan path is
recorded by early andalusite succeeded by sillimanite;
cordierite is widespread, whereas staurolite and espe-
cially garnet are less common, or absent.
Ocean-ridge metamorphism (or alteration, as some
would prefer) is a globally significant interaction be-
tween seawater and hot basaltic rock at spreading
oceanic rifts. Metasomatism results in mineral assem-
blages resembling those of the zeolite, prehnite–
pumpellyite, greenschist, and locally amphibolite
facies. But the reconstitution is patchy, more or less
monomineralic veins are widespread, and the mineral
zonation is telescoped within the upper few kilometers
of the seafloor in pillow lavas and underlying sheeted
dike complex. Metasomatism creates metal sulfides
and releases silica for seafloor chert deposits.
The most intact oceanic lithosphere exposed on
land is found in a few large slabs of ophiolite, such as
the Semail in Oman. These ophiolites appear to have
been created in back-arc basins underthrust by nearby
subducting continental margins that subsequently
buoyed upward, lifting the overriding oceanic rocks
above sealevel.
Terranes of arc-trench sedimentary deposits
(graywacke), mélange, high P/T facies series rocks,
Metamorphism at Convergent Plate Margins: P–T–t Paths, Facies, and Zones
607