
3 SOLAR COLLECTOR TECHNOLOGIES AND SYSTEMS
741
Solar Systems Ltd.
Luz International Limited (Luz) is the world's leading
developer of parabolic trough solar electric systems. 9 large
commercial-scale solar power plants have been built by
Luz in the California Mojave Desert between 1984 and
1990. These plants, which continue to operate on a daily
basis, range in size from 14 to 80 MW and representing a
total of 354 MW of installed electric generating capacity.
The HCE is one of the most important elements to convert
the solar energy into thermal energy, and its thermal
performance decides the thermal efficiency of solar thermal
power station. The cost of receiver is about 20% of the total
costs in the solar power station [4]. From the operation and
maintenance statistics of the 9 parabolic trough solar
thermal power plants in the USA [5], there are 30-40%
failure of the HCEs at SEGS VI-IX for 9 to 11 years of
operation, because of thermal stresses in the glass-to-metal
seals joint, which cause vacuum loss, fracture of the glass
tube and solar selective coating degradation in air. It is not
economic to directly replace destroyed module, replacement
cost is about 1000$ / HCE (evacuated), because many of
them are welded together to build one loop. For repairing the
tubes, the whole loop has to be shut down. So the
glass-to-metal seal of HCE failure/degradation is the single
largest cost factor in the solar power system, which also
results in the system efficiency reduction.
2. INTRODUCTION
The glass-to-metal sealing of the HCE is a type of tubular
sealing, it requires not only certain mechanical strength, but
also excellent gas tightness under high vacuum condition.
Glass and metal are two kinds of materials which are
thoroughly different character with each other, if they are
required to make hermetic glass-to-metal seal, there are
several basic conditions to meet as follows:
2.1 Thermal Expansion Coefficients
The thermal expansion coefficient of metal is always
constant under the condition that there is no phase change
of metal. But the thermal expansion coefficient of glass will
increase when the temperature of glass exceeds the
annealing temperature, and it is not important when the
temperature arrives at the softening temperature, because
glass will become viscosity liquid and the thermal stresses
are able to automatically vanish, if the differences in
coefficients of expansion of the glass and metal do not
exceed ±10% [6] from the room temperature to the glass
annealing temperature range, the expansion curves of the
glass and metal are as far as possible consistent, the stresses
in the glass do not exceed its tensile strength.
If the expansion speeds and contraction speeds of the glass
and metal are dissimilar, both can produce the stresses in
the sealing body, when the stress value surpasses the
intension of the glass, the sealing joint will crack and
causes the evacuated tube leakage, even if it has not
cracked in the short time, but with the time going, it will
also gradually produce the microcrack and form the chronic
leakage as a result of stresses function. When the vacuum
tube is vibrated or collided, the microcrack can rapidly
spread and expand then the tube will damage.
2.2 Wettability
Wettability reflects contact abilities between two kinds of
material. In order to achieve fine hermetic sealing, it is very
important to let both the glass and metal have excellent
wetting ability each other. The glass to metal wettability is
the same as the principle of the wettability between a
droplet of the liquid on a horizontal solid surface, the
wettability of a solid by a liquid is characterized in terms of
the angle of contact that the liquid makes on the solid.
Depending on the type of surface and liquid, the droplet
may take a variety of shapes as illustrated in figure 2, The
condition θ>90°indicates that the solid is wet by the liquid,
and θ<90° indicates nonwetting, with the limits θ=0 and
θ=180° defining complete nonwetting and complete
wetting, respectively. The principle of wettability is the
very basic technology of the glass-to-metal seals. In general,
it is nonwetting between glass and pure metal, but when
there is a metallic oxide film on the surface of metal, the
wettability becomes very fine.
Fig. 2: A liquid droplet in equilibrium with a horizontal
surface.