
566 9 Magma Transport
where the characteristics enter the domain. The physically appropriate condition
would seem to be
φ =0on∂D
−
, (9.54)
where ∂D
−
denotes that part of the boundary ∂D of D on which u.n < 0, where n
is the outward normal to D, and this appears consistent with the choice of apparent
characteristics for (9.51), if this is written in the form (using (9.50))
δ
−1
∂
∂t
+u.∇
(z +˜νψ −δφ) =φψ +rφ
t
+ε∇
2
ψ. (9.55)
If this is an appropriate condition for φ, then the elliptic (9.47)
3
suggests that
ψ should be prescribed on ∂D, except where φ = 0 and the elliptic term for ψ is
degenerate. Since the melting temperature is T
0
+Γp
l
in the partially molten region,
while it is T
0
+ Γp
s
in the cold mantle, it seems we should ensure continuity of
temperature by having p
l
=p
s
on ∂D,i.e.ψ =0on∂D (φ =0). The two boundary
conditions can be combined in the form
φψ =0on∂D. (9.56)
While this is plausible, it is by no means certain, and one might expect the non-
degenerate elliptic ψ term in (9.55) to require ψ to be prescribed everywhere. This
is an example of a model where some functional analysis would actually be useful.
A further difficulty is that to say the melting temperature in the cold mantle is
T
0
+ Γp
s
carries in itself no meaning, since equilibrium melting temperature is
defined through thermodynamic equilibrium at the interface. In addition, we should
add that (9.56) has not been systematically derived from any physical principle. We
now attempt to resolve this latter issue.
9.4.4 Thermodynamic Equilibrium
At the microscopic interface between partially molten and cold mantle ∂D,were-
quire that the jump in temperature, pressure and Gibbs free energy be zero:
[T ]
m
c
=[p]
m
c
=[G]
m
c
=0. (9.57)
The first of these is standard, the second is a force balance (it should properly be a
balance of normal stress, but we omit deviatoric stresses for simplicity), while the
third is the condition of thermodynamic equilibrium, and it is this condition which
we need to prescribe, instead (perhaps) of (9.56).
Consider first a reference state in which p
s
= p
l
in the partial melt region. The
Gibbs free energy of each separate phase depends on temperature and pressure, and
we can write for the partial melt side of ∂D, G =G
m
, where
G
m
=φ(h
l
−TS
l
) +(1 −φ)(h
s
−TS
s
), (9.58)