
530 8 Mantle Convection
that of the chemical structure of the mantle. There are two aspects to this. The most
fundamental is that as depth increases in the mantle, there are a number of phase
changes which occur. The upper mantle below the lithosphere is largely thought to
consist of olivine, (Mg,Fe)
2
SiO
4
, and this undergoes a transformation to a spinel
phase between 400 and 500 km depth. A further transition occurs at 650 km, where
the spinel dissociates into a perovskite phase (Mg,Fe)SiO
3
and wüstite (Mg,Fe)O.
Depending on the exact composition, other phase changes may occur at different
pressures. In the mantle, the presence of these phase changes is detected seismi-
cally, and they are associated with density increases of several percent (Anderson
2007).
(Some) descending lithospheric slabs clearly sink (at least) to the vicinity of the
650 km seismic discontinuity, so a reasonable initial simplifying assumption may
be that of a two layer mantle, with the olivine in the upper mantle separated from
the perovskite lower mantle. The simplest consequence would seem to be that con-
vection might occur separately in two, or possibly more, layers. In fact, this idea
underlies the original concept of shallow mantle convection, and underpinned the
choice of depth scale in models such as that of Turcotte and Oxburgh (1967). Later
investigations raised doubts that the density jump would be sufficient to prevent
whole-mantle convection, and many studies now assume this. The issue revolves
round the magnitudes of the relative density jump across a phase change boundary,
ρ
ρ
, the corresponding buoyancy term αT , and the slope of the Clapeyron curve
relating the phase change pressure to the temperature. At least for the descending
lithospheric slabs, we may take T ∼ 10
3
K, and thus αT ∼ 3 × 10
−2
.This
may be comparable to the density increase across the 650 km boundary. Numerical
studies (Christensen and Yuen 1984, 1985) suggest that at least some form of pene-
tration is likely, and this is consistent with ideas of hot spots associated with plumes
originating at the core–mantle boundary.
However, layered convection seems the easiest explanation for the inference,
from geochemical studies of different magmas at the surface of the Earth, that the
mantle consists of at least two, and possibly more, distinct reservoirs, which have
been chemically isolated for much of the Earth’s history (Tackley 2009). This in-
ference is based on the different trace elements present in the erupted magmas.
Mid-ocean ridge basalts (MORB) are depleted in the so-called incompatible trace
elements, while the continental crust is enriched in these same elements, which leads
us to suppose that the continents form as the residue from continual melting of the
MORB source region. Mass balance calculations suggest that this source only oc-
cupies around half the mantle (the estimates vary a good deal). The easiest vision
is to suppose that the phase change at 650 km causes a form of ‘leaky’ (see below)
layered convection, thus providing the separate mantle reservoirs.
However, this simple picture is increasingly complicated by further geochemi-
cal signatures. One such is that ocean island basalts (OIB, such as Hawaii) have
anomalous helium isotope ratios, suggesting that they originate from a primordial
reservoir. Most simply, this is construed to be the lower mantle, and that is consistent
with the idea that they come from mantle plumes, which presumably penetrate the
barrier at 650 km. Various other complications arise, and have led to various differ-
ent conceptualisations of how convection works in practice. It is important to note