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Dynamical Systems and Thermodynamics
A Carati, L Galgani and A Giorgilli, Universita
`
di
Milano, Milan, Italy
ª 2006 Elsevier Ltd. All rights reserved.
Introduction
The relations between thermod ynamics and
dynamics are dealt with by statistical mechanics.
For a given dynamical system of Hamiltonian type
in a classi cal framework, it is usually assumed that a
dynamical foundation for equilibrium statistical
mechanics, namely for the use of the familiar
Gibbs ensembles, is guaranteed if one can prove
that the system is ergodic, that is, has no integrals of
motion apart from the Hamiltonian itself. One of
the main consequences is then that classical
mechanics fails in explaining thermodynamics at
low temperatures (e.g., the specific heats of crystals
or of polyatomic molecules at low temperatures, or
the black body problem), because the classical
equilibrium ensembles lead to equipartition of
energy for a system of weakly coupled oscillators,
against Nernst’s third principle. This is actually the
problem that historically led to the birth of quantum
mechanics, equipartition being replaced by Planck’s
law. At a given temperature T, the mean energy of
an oscillator of angular frequency ! is not k
B
T (k
B
being the Boltzmann constant), and thus is not
independent of frequency (equipartition), but
decreases to zero exponentially fast as frequency
increases.
Thus, the problem of a dynamical foundation for
classical stat istical mechanics would be reduced to
ascertaining whether the Hamiltonian systems of
physical interest are ergodic or not. It is just in this
spirit that many mathematical works were recently
addressed at proving ergodicity for systems of hard
spheres, or more generally for systems which are
expected to be not only ergodic but even hyperbolic.
However, a new perspective was opened in the year
1955, with the celebrated paper of Fermi, Pasta, and
Ulam (FPU), which constituted the last scientific
work of Fermi.
The FPU paper was concerned with numerical
computations on a system of N (actually, 32 or 64)
equal particles on a line, each interacting with the
two adjacent ones through nonlinear springs, certain
boundary conditions having been assigned (fixed
ends). The model mimics a one-dimensional crystal
(or also a string), and can be described in the
familiar way as a perturbation of a system of N
normal modes, which diagonalize the corresponding
linearized system. The initial conditions corre-
sponded to the excitation of only a few low-
frequency modes, and it was expected that energy
would rather quickly flow to the high-frequency
modes, thus establishing equipartition of energy, in
agreement with the predictions of classical equili-
brium statistical mechanics. But this did not occur
within the available computation times, and the
Dynamical Systems and Thermodynamics 125