
21-28
REFERENCE
DATA
FOR ENGINEERS
photocurrent to generation rate is called the photocon-
ductive gain.
The photoconductive gain of a pure material can
often be greatly increased by addition of localized traps
lying near the conducting band. Since these are in
thermal equilibrium with the conducting band, they
serve as an additional reservoir of the charge carriers.
This can increase both the response time and the
sensitivity by a large factor.
Practically all materials are photoconductors in the
sense that light of the correct wavelengths will generate
current carriers. However, in many materials the photo-
conductivity is not detectable by ordinary measure-
ments, either because of very short carrier lifetimes or
because of a large dark current. The useful photocon-
ductors, characterized by comparatively long lifetimes
and low dark currents, have most of their charge carriers
immobile (in the dark). Light of the proper energy can
excite these carriers through the forbidden energy
regions into the conduction bands. The long-wavelength
limit of photoconductivity at low temperatures is given
approximately by
A,,,
=
hc/E,
where,
E,
is the forbidden band gap,
h
is Planck’s constant,
c
is the velocity of light.
For wavelengths longer than
5
micrometers, this equa-
tion gives a band gap smaller than
‘/4
electronvolt.
Photoconductors with such small energy gaps are
usually cooled to reduce the dark conductivity due to
thermal excitation of carriers across the gap.
Values
of
D*,
a commonly used figure of merit for
photoconductors, for several typical photoconductors at
room temperature are shown in Fig.
24.
The photocon-
ductors with long-wavelength cutoffs will be considera-
bly more sensitive if they are cooled below room
temperature.
Photodiodest-When photons irradiate a semicon-
ductor having a band gap less than the energy of the
photons, hole-electron pairs are produced. By forming
a pn junction
in
a semiconductor, those hole-electron
pairs can be collected. The resulting photodiode may
have a quantum efficiency (ratio of collected photoelec-
trons to impinging photons) of from
0.2
to
0.7
or higher
with antireflection coating.
Photodiodes have two primary operating modes, the
photovoltaic mode and the reverse-biased mode that is
often referred to incorrectly as the photoconductive
mode. In the photovoltaic mode, the unbiased junction
is illuminated to stimulate the production of hole-
?
Stillman,
G.
E.,
and
Wolfe,
C.
M.,
“AvalanchePhotodi-
odes,” in
Semiconductor and Semimetals,
Vol.
12
(New
York:
Academic Press,
Inc.,
1977;
pp. 291-393).
electron pairs. Charge separation then occurs in the
field of the junction, and a current and/or voltage
results. Since photovoltaic cells produce a short-circuit
photocurrent that is linear with respect
to
the radiation
incident upon the pn junction, they are well suited for
low-level light detection and measurement. This is
especially true for narrow-band-gap materials and de-
vices where the leakage current of reverse-biased diodes
is often high enough to contribute undesirable noise.
In
the figures where the
D*
limit for ideal photovoltaic
detectors is shown, this refers to short-circuit photovol-
taic detectors or reverse-biased photodiode detectors. If
the photovoltaic detectors are operated in the open-
circuit mode, the limiting
D**
is the same as that shown
for ideal photoconductive detectors, since in this case
the recombination of carriers in the open-circuit photo-
voltaic detector contributes noise
just
as in photocon-
duction.
10“
1
I
i
i
i
iiii
I I
2a
STERADIANS FIELD
OF
VIEW
295
K
BACKGROUND TEMPERATURE
c
k
2
8
2
109
u.
8
F-
a
v,
108
1
2
3
4
5
678910
20
30
40
WAVELENGTH IN MICROMETERS
10’’
10“’
I I
,
I
VI
IYI
I II
Fig.
26. Spectral detectivities
of
several semiconductor
detectors.
(Santa Barbara Research Center data.)
The major application for photovoltaic cells, howev-
er, is the conversion of solar radiation into electrical
power. The operating specification of most interest in
this application
is
the power conversion efficiency (ratio
of
the power produced by the cell to the power in the
incident photon flux). Cell efficiency is affected by such
factors as surface reflectance, absorption between the
surface and the pn junction, and transmissivity of the
junction region. Power efficiencies
of
commercial solar