
OPTOELECTRONICS
21-11
nium, both indirect band-gap materials, produce far too
little recombination radiation for practical use, but
other direct and indirect band-gap materials
or
direct-
indirect band-gap alloys, particularly GaAs, GaP, and
solid solution alloys of GaAs and GaP, GaAs and
AlAs, and InAs and GaP, can be tailored to produce
relatively efficient radiative recombination.
Gallium arsenide (GaAs) LEDs and similar direct
band-gap LEDs in other materials exhibit internal
quantum efficiencies (ratio of emitted photons per
injected electrons) very nearly unity. Due to such
factors as internal absorption, contact shadows, and
refractive-index-induced surface reflectance, the exter-
nal quantum efficiency of practical LEDs is usually
much lower (less than about
0.1).
Both quantum
efficiency and recombination radiation wavelength are
affected by temperature, and the external quantum
efficiency of specially fabricated LEDs may exceed
0.4
at
20
K.
Wavelength is directly related to junction
temperature and typically varies about
0.25
nm per
degree Celsius. Therefore, changes in either the ambi-
ent temperature or junction heating will alter the
emitted wavelength.
A
wide range of economical long-lived plastic- and
metal-packaged LEDs is commercially available. It
is
common practice to install the diode chip inside a
miniature directional reflector and encapsulate the en-
tire assembly in
an
index-matching epoxy to enhance
the radiation extraction efficiency. This fabrication
technique improves the external efficiency by a factor of
2
or more. Visible emitters suitable for use as visual
indicators and other display roles include: GaP and
GaP:N (green-550 nm); G~AS~,~~P,,~~:N (yellow-
610 nm); GaAso.bP0,, (red-660 nm); Alo,3Gao,7As
(red-675 nm); and GaP:Zn,
0
(red-690 nm). Sever-
al of these materials, particularly G~AS~,~P~,~, are in
widespread use as display devices for digital clocks,
watches, calculators, and electronic instruments. The
most common infrared-emitting materials have been
GaAs (905 nm) and GaAs:Si (940 nm). Until recently,
these materials offered much higher efficiencies than
visible emitters. They are useful in such applications as
optical communications and ranging, position sensing,
object detection, and electro-optical isolation. Ordinary
GaAs LEDs
are
characterized by a reasonable power
output (about
1.5
mW
@
100 mA
IF)
and fast turn-on
time (about 1 ns), whereas special GaAs diodes doped
with Si are more efficient (about
10
mW
@
100
mA
IF)
but slower
(ton
of
about
300
ns). Since the radiant
emission from electroluminescent diodes is generally
linear with respect to applied current below the satura-
tion region, they can be easily and directly pulse or
analog modulated by simply controlling the forward
bias. Electroluminescent diodes of GaAs, GaAs:Si,
GaAs-Al,Ga,-,As, and related materials emitting in
the near infrared (approximately 750-950 nm) have
found wide use in fiber-optical communication applica-
tions, but because of lower fiber losses in the
1.3-
to
1.6-pm wavelength range, InGaAsP and InGaAs LEDs
are being rapidly developed for use at these longer
wavelengths.
Electroluminescent diodes normally emit radiation in
a relatively broad pattern and therefore cannot be
coupled to optical waveguide fibers as efficiently as the
laser sources described below. Nevertheless, reasonable
coupling efficiency can be obtained by utilizing epoxy
lenses or special structures such as the
Burrus
diode
structure shown in Fig. 9. This structure has a typical
emission area of
2
X
cm2 and a radiance
of
100
W/sr/cm2 at a forward bias of
150
mA.
The output
wavelength can be peaked anywhere between
750
and
905 nm by adjusting the aluminum concentration in the
Al,GaI-,As alloy making up the diode. About
2
mW
can be coupled into a suitable optical waveguide fiber
when this structure is used. This and most other
electroluminescent diodes exhibit operating lifetimes of
more than
lo4
hours at the relatively high current
densities required to obtain significant optical output.
High-Intensity Visible
LEDs
A typical package commonly used for LEDs is shown
in Fig.
10.
This device is a Hewlett Packard Optoelec-
tronic Division high-power LED fabricated from AIIn-
GaP and packaged with an epoxy lens. This material
has very high luminous efficiency, and AlInGaP devices
are capable of producing high light output over a wide
range
of
drive currents. The package shown incorpo-
rates an advanced optical design that produces an
extremely high peak intensity in a viewing angle
as
narrow as three degrees. The emission
of
these AlIn-
GaP LEDs occurs in a narrow spectral range and can be
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Fig.
9.
GaAs electroluminescent diode specifically designed
for direct coupling to an optical-fiber waveguide.
(After
Burrus, C.
A.,
and Dawson,
R.
W.,
“Small-Area High-
Current-Density
GaAs
Electroluminescent Diodes and a Meth-
od
of
Operation for Improved Degradation Characteristics,”
Applied Physics Letters,
I
August
1970,
pp.
97-99.)