
of atoms from one part of a grain to another. The
driving force for this diffusion is a gradient in chemical
potential from high- to low-stress sites (Green, 1980).
In general, grains shorten parallel to the maximum
compressive stress axis and lengthen parallel to the
minimum compressive stress (Section 8.1.1). The flat-
tened grains impart a foliation to metamorphic rocks.
Deformation by diffusive transfer has a rheologic
behavior resembling that of Newtonian viscosity where
the time rate of strain is proportional to the applied
shear stress (Section 8.1.3). Like viscous flow, diffusive
transfer is a slow continuous deformation that occurs
under steady shear stress at low strain rates, hence the
appellation diffusive creep.
Three possible creep processes correspond to the
three different diffusion paths in grain aggregates (Fig-
ure 17.1) that have contrasting rates. Diffusion through
the volume of the grain is Nabarro–Herring creep, dif-
fusion along dry grain boundaries is Coble creep, and
via an intergranular fluid is pressure solution.
All three diffusion paths are effective at relatively
high temperatures but other thermally activated mech-
anisms of ductile flow are likewise enhanced and may
supersede the effects of diffusive transfer and creep.
Hence, diffusive creep is generally manifest at relatively
low temperatures of metamorphism, limited perhaps
to the upper greenschist facies. In generally coarser
grained, higher grade metamorphic rocks, paths of dif-
fusion are lengthened and there is proportionately less
surface area to volume; both factors decrease the effect-
iveness of diffusive transfer. In addition, higher grade
rocks may have little fluid in them as a result of pro-
grade devolatilization reactions. Locally, however, as in
brittle fault and ductile shear zones, grain size can be
reduced by cataclasis (Section 8.2.1 and Figure 8.7)
and by dynamic recrystallization (discussed later),
respectively. In these sheets of deformed rock, strain
can be enhanced by diffusive creep.
Pressure Solution. Probably the most effective mech-
anism of diffusive creep is pressure solution because
of the enhanced kinetics where intergranular fluids are
present.
The work of stressing a crystal imparts increasing
energy as strain is locked in; equilibrium atomic bond
angles and distances are changed. In the presence of a
fluid, a stressed, higher-energy crystal is more soluble
relative to neighboring ones in the communicating
fluid that are not stressed and the surface of a single
grain where the normal stress is greatest is more
soluble than where the stress is less. As a result of this
Riecke’s principle, higher concentrations of dissolved
chemical species are created in intergranular fluids
adjacent to more stressed grains or grain parts. The
resulting concentration (activity) gradient drives ionic
diffusion from more stressed grain margins to less
stressed surfaces where grain growth takes place. In a
nonhydrostatically stressed rock permeated by an inter-
granular fluid, this differential pressure solution can
produce a significant change in shape of the rock body.
Pressure solution depends on the availability of relat-
ively soluble minerals under metamorphic conditions,
the most common of which are calcite and quartz. The
necessary fluid can be derived from different sources
(Section 16.6.1), but fluid-liberating compaction and
prograde reactions are probably significant.
Pressure solution can be manifest in different ways
in rocks. It locally creates a significant loss in rock
volume. In some conglomerates, depressions on the
surfaces of clasts are created by the pressure of neigh-
boring impinging clasts causing pressure solution. In
fine-grained sedimentary and low-grade metamorphic
rocks, dissolution surfaces are repetitively spaced
surfaces millimeters to centimeters apart that define a
spaced cleavage (Section 15.1.1; see also Twiss and
Moores, 1992, Chapter 13). Some of these dissolution
surfaces give a false impression of differential shear
movement parallel to the surface (Figure 15.4).
Irregular stylolites in carbonate rocks where fossils are
sharply truncated are examples. In low-grade meta-
morphic rocks, less soluble phyllosilicates and other
“inert” minerals, such as zircon, can be concentrated
along discrete crenulation cleavages where relatively
more soluble quartz has been preferentially dissolved
and removed (Figure 15.3). Pressure solution can also
be manifest on a pervasive grain scale throughout a
rock, imparting a penetrative foliation. Thus, flattened
quartz grains in some schists and phyllites have a film
of insoluble residue on the flat margins and fibrous
overgrowths (“beards”) on the extended margins (Fig-
ure 17.10). These overgrowths resemble mineral pre-
cipitates in the lower stress pressure shadows alongside
rigid objects such as boudins (Figure 15.8b).
The existence of interconnected fluid pathways
along grain boundaries is essential for pressure solu-
tion. Under hydrostatic states of stress, H–O–C fluids
in aggregates occur in isolated pools at grain corners
where the dihedral angle 60° and possibly in tubes
along three grain edges where the dihedral angle 0°
60°. However, Tullis et al. (1996) have demon-
strated experimentally that in feldspar aggregates un-
der nonhydrostatic stress at elevated P and T most grain
boundaries are fully wetted, or the fluid is a continuous
film covering the entire grain boundary; the dihedral
angle is effectively equal to 0°. This deformation-
induced fluid wetting of grain surfaces reduces the
yield strength of the aggregate while increasing the
diffusive transport rate, both by about an order of mag-
nitude. Diffusive creep is promoted at the expense of
plastic dislocation creep, which otherwise prevails at the
P and T of the experimental conditions. Deformation-
enhanced pressure solution accomplishing diffusive
530 Igneous and Metamorphic Petrology