238 Measurement and Data Analysis for Engineering and Science
measurand values are recorded for multiple samples. The random error de-
termined from a series of repeated measurements in a timewise experiment
performed under steady conditions results from small, uncontrollable fac-
tors that vary during the experiment and influence the measurand. Some
errors may not vary over short time periods but will over longer periods.
So, the effect of the measurement time interval must be considered [5]. In
the analogous sample-to-sample experiment, the random error arises from
both sample-to-sample measurement system variability, and variations due
to small, uncontrollable factors during the measurement process.
Errors that are not related directly to measurement system errors can be
identified through repeating and replicating an experiment. In measurement
uncertainty analysis, repetition implies that measurements are repeated
in a particular experiment under the same operating conditions. Replica-
tion refers to the duplication of an experiment having similar experimental
conditions, equipment, and facilities. The specific manner in which an ex-
periment is replicated helps to identify various kinds of error. For example,
replicating an experiment using a similar measurement system and the same
conditions will identify the error resulting from using similar equipment. The
definitions of repetition and replication differ from those commonly found
in statistics texts (for example, see [14]), which consider an experiment re-
peated n times to be replicated n + 1 times, with no changes in the fixed
experimental conditions, equipment, or facility.
The various kinds of errors can be identified by viewing the experiment
in the context of different orders of replication levels. At the zeroth-
order replication level, only the errors inherent in the measurement system
are present. This corresponds to either absolutely steady conditions in a
timewise experiment or a single, fixed sample in a sample-to-sample ex-
periment. This level identifies the smallest error that a given measurement
system can have. At the first-order replication level, the additional random
error introduced by small, uncontrolled factors that occur either timewise
or from sample to sample are assessed. At the N th-order replication level,
further systematic errors beyond the first-order level are considered. These,
for example, could come from using different but similar equipment.
Measurement process errors originate during the calibration, measure-
ment technique, data acquisition, and data reduction phases of an experi-
ment [5]. Calibration errors can be systematic or random. Large systematic
errors are reduced through calibration usually to the point where they are
indistinguishable with inherent random errors. Uncertainty propagated from
calibration against a more accurate standard still reflects the uncertainty of
that standard. The order of standards in terms of increasing calibration er-
rors proceeds from the primary standard through inter-laboratory, transfer,
and working standards. Typically, the uncertainty of a standard used in a
calibration is fossilized, that is, it is treated as a fixed systematic error
in that calibration and in any further uncertainty calculations [13]. Data
acquisition errors originate from the measurement system’s components,