13-52 The Civil Engineering Handbook, Second Edition
or HF) in the combustion gas will dissolve in the condensed aqueous liquid, corroding the tubes. HCl
is especially corrosive to metals, including most forms of stainless steel. HF is also corrosive to metals,
but it attacks silica-based refractory. SO
2
is relatively insoluble in water and is relatively noncorrosive;
however, it lowers the dewpoint of water substantially, and its presence requires that the boiler be operated
at a higher temperature to prevent condensation. To minimize the risk of condensation, boilers are
typically sized so that the temperature of the exit gas is above 450°F. Furthermore, because of the
particularly corrosive nature of HF on refractory materials, the presence of more than trace amounts of
fluorides may prevent the use of boilers.
A final consideration in the use of heat recovery boilers is chlorodibenzodioxins and chlorodibenzo-
furans formation. These contaminants have been found to form at temperatures in the 200 to 370°C
(400 to 700°F) range, which is the same operating range creating the risk of these hazardous materials
forming in the boiler and on the boiler surfaces.
Acid gas control devices are of two types, wet and dry. The wet devices include packed bed scrubbers,
Venturi and Venturi-like scrubbers, “wet” electrostatic precipitators, and proprietary wet scrubbers. Dry
particulate removal devices include fabric filters, electrostatic precipitators, and high-efficiency particulate
absolute (HEPA) filters. HEPA filters are used for particulate control, where a high level of particulate
removal is required, such as in radioactive waste incinerators. They are similar in operation to fabric
filters, although the nature of the fabric is such that a high level of particulate control is achieved. Wet
devices remove acid gases as well as particulate, and the two functions are often combined in one device.
Dry scrubbing is a technique whereby lime or another lime-based sorbent is injected into the hot zone
of the incinerator. The sorbent removes a fraction of the acid gas in suspension and is collected on the
particulate removal device, usually a fabric filter. Dry scrubbers are usually used in conjunction with
another form of acid gas removal device.
Electrostatic Precipitators
Electrostatic precipitators (ESPs) can be used for two entirely different types of service. “Wet” precipitators
can be used as the principal particulate control device within a wet scrubbing system including a gas
cooler and an acid gas absorber. While basic operating principles of the wet and conventional ESP are
similar, the two different styles are subject to quite different operating problems. They both use the
principle of electrostatic attraction. The incoming particulate is ionized and then collected on charged
plates. In a dry precipitator, the plates are periodically rapped or shaken, and the accumulated dust is
collected in hoppers at the bottom. In a wet precipitator, a continuous stream of recirculated liquor
drains over the plates and removes the accumulated particulate matter. A wet ESP can be used to control
acid gas as well as particulate. Wet ESPs operate at relatively low gas temperatures, and the precipitators
are limited to one or two electrical fields in series.
Figure 13.9 is a drawing of a conventional dry electrostatic precipitator. In electrostatic precipitators,
particles are electrically charged during passage through a strong, nonuniform electrical field. The field
is generated by a transformer-rectifier set that supplies pulsed D.C. power to a set of small diameter
electrodes suspended between grounded collection plates. Corona discharges on these electrodes generate
electron flow, which in turn, leads to the formation of negative ions as the electrons travel on the electrical
field lines toward the grounded plates. The negative ions also continue on the field lines toward the plates.
Within the corona itself, positive ions form, and these travel back to the high-voltage electrodes.
An ESP’s performance depends on the ability of the particulate matter to receive and maintain a charge,
the velocity of the particulate migration to the collection plates, the ability of the particulate to adhere
to the plates after they are captured, and the ability of the system to minimize re-entrainment of the
particulate during the cleaning or rapping cycle.
The ability of the particulate to maintain a charge and to adhere to the collection plates is a function
of the resistivity of the particulate and of the flue gas. The resistivity is a measure of the ability of electrical
charges on the particles to pass through the dust layer to the grounded collection plates. Dust layer