Drawing. At temperatures to approximately 120 °C (250 °F), soap-base lubricants, fatty esters, polymer additives in oil
and water, and pastes formulated with chlorinated additives are successful lubricant systems. At temperatures in excess of
120 °C (250 °F), the choice of lubricant is restricted to synthetic fluids formulated with soap, fatty esters, and/or
chlorinated compounds. Above 230 °C (450 °F), graphite and/or molybdenum disulfide in various carriers are preferred.
Spinning. At elevated temperatures, the synthetic fluids compounded with graphite and/or molybdenum disulfide are
applied. Water carriers for the solid lubricants may be preferred to reduce the occurrence of smoke and the possibility of
fire.
Forming of Nickel and Nickel-Base Alloys
These metals are difficult to wet with lubricants; thus heavy-duty lubricants with exceptional film-priming characteristics
are necessary for effective lubrication. On the other hand, lubricants containing sulfur, chlorine, or solid additives such as
zinc oxide or lead carbonate can, if not removed from the nickel surface, can cause embrittlement of the metal.
Shearing, Blanking and Piercing. Oils incorporating sulfur- or chlorine-containing additives may be used. Water-
base lubricants of similar composition may be applied if they are removed as soon as possible after forming to prevent
embrittlement. Fatty esters and polymers have grown in application as components of formulated lubricants.
Deep Drawing. Soap-base pastes as well as oils with fatty esters, amides, and/or sulfur and chlorine additives have
been used. Emulsions fortified with amides and polymers also have been formulated and applied.
Spinning. Pigmented pastes and chlorinated wax in oils are successful lubricants. Plain waxes and soaps are frequently
important components of these lubricants.
Forming of Titanium Alloys
Galling of titanium alloys is a particular problem because of the affinity of the metal for die materials. Notch sensitivity
and embrittlement may also lead to splitting or cracking of formed parts. Cold and warm forming may be carried out with
suitable films designed to prevent metal-to-metal contact. Frequently, overlays of steel sheet or plastic sheet are used with
an auxiliary lubricant.
Deep Drawing. Overlays are often used with oil-base lubricants formulated with chlorinated waxes. Oxidized or
phosphated coatings are successful in relatively severe drawing operations at elevated temperatures. Graphite and/or
molybdenum disulfide in oil may be used.
Roll Forming. Oils compounded with sulfurized or chlorinated fats are used. Oil- or water-soluble polymers may also
be added. Chlorinated waxes, high molecular weight waxes, or polymers soluble in oil may be effective for relatively
moderate deformation.
Spinning. Colloidal graphite and/or molybdenum disulfide blended in oil may be used at temperatures up to
approximately 205 °C (400 °F). Chlorinated wax and/or sulfurized fat in oil also may serve as lubricants. At higher
temperatures, fillers such as bentonite or mica with graphite and/or molybdenum disulfide formulated into a grease are
used successfully.
Forming of Platinum-Group Metals
Surface contamination due to metal contact at surfaces with iron or other metals may adversely affect surface integrity
and electrical resistivity. Separation of tool and workpiece by an appropriate lubricant film is critical. Platinum and
palladium can be formed by most standard sheet metal forming operations (blanking, piercing, and deep drawing). Cold
welding of the workpiece to the tooling must be avoided, and therefore continuous lubricant films are important in
operation. Many of the lubricants used for forming copper alloys may also be used for forming platinum and palladium.
Rhodium and iridium are more difficult to form, and ruthenium and iridium are extremely difficult to form.