
262 Refrigeration Systems and Applications
The principle of operation of a solar-powered absorption cooling system is the same as that of
the absorption cooling system shown in Figure 4.33, except for the heat source to the generator. In
Figure 4.33, we presented a solar absorption cooling system using an R-22 (refrigerant)-DMETEG
(absorbent) combination as a working fluid (Dincer et al., 1996). Its operation can be briefly
explained as follows. In the absorber, the DMETEG absorbs the R22 at the low pressure and
absorber temperature supplied by circulating water, and hence a strong solution occurs (2). This
strong solution from the absorber enters a solution pump, which raises its pressure and delivers
the solution into the generator through the heat exchanger (3–6). The generator, which is heated
by a solar hot water system, raises the temperature of the strong solution, causing the R-22 to
separate from it. The remaining weak solution flows down to the expansion valve through the heat
exchanger and is throttled into the absorber for further cooling as it picks up a new charge of
the R22 vapor, becoming a strong solution (6−2) again. The hot R-22 vapor from the generator
passes to the condenser and is released to the liquid phase (8–9). The liquid R-22 enters the second
heat exchanger and loses some heat to the cool R-22 vapor. The pressure of the liquid R-22 drops
significantly in the throttling valve before it enters the evaporator. The cycle is completed when
the desired cooling load is achieved in the evaporator (10–12). Cool R-22 vapor obtained from the
evaporator enters the absorber while the weak solution comes to the absorber continuously. The
R-22 vapor is absorbed here (12−1). This absorption activity lowers the pressure in the absorber,
causing the vapor to be taken off from the evaporator. When the vapor goes into liquid solution,
it releases both its latent heat and a heat of dilution. This energy release has to be continuously
dissipated by the cooling water.
Solar-operated ARSs have so far achieved limited commercial viability because of their high
cost–benefit ratios. The main factor which is responsible for this drawback is the low COP associated
with these systems, which generally operate on conventional thermodynamic cycles with common
working fluids. It is essential to investigate the possibility of using alternative working fluids
operating in new thermodynamic cycles. Also, development of more efficient, less expensive solar
collectors will be a continuing need for solar energy to reach its full potential.
5.10 Magnetic Refrigeration
Magnetic refrigeration is a cooling technology based on the magnetocaloric effect. This technique
can be used to attain extremely low temperatures (well below 1 K) as well as the ranges used
in common refrigerators, depending on the design of the system. The magnetocaloric effect is a
magneto-thermodynamic phenomenon in which a reversible change in temperature of a suitable
material is caused by exposing the material to a changing magnetic field. One of the most notable
examples of the magnetocaloric effect is in the chemical element gadolinium and some of its alloys.
Gadolinium’s temperature is observed to increase when it enters certain magnetic fields. When it
leaves the magnetic field, the temperature returns to normal.
In the magnetic refrigeration cycle, depicted in Figure 5.33, initially randomly oriented magnetic
moments are aligned by a magnetic field, resulting in heating of the magnetic material. This heat is
removed from the material to the ambient temperature by heat transfer. On removing the field, the
magnetic moments randomize, which leads to cooling of the material below ambient temperature.
Heat from the system to be cooled can then be extracted using a heat-transfer medium. Depending
on the operating temperature, the heat-transfer medium may be water (with antifreeze) or air, and
for very low temperatures, helium.
Magnetic refrigeration is an environmentally friendly cooling technology. It does not use ozone-
depleting chemicals (CFCs), hazardous chemicals (NH3), or greenhouse gases (hydrochlorofluoro-
carbons [HCFCs] and hydrofluorocarbons [HFCs]). Another key difference between vapor cycle
refrigerators and magnetic refrigerators is the amount of energy loss incurred during the refrig-
eration cycle. The cooling efficiency in magnetic refrigerators working with gadolinium has been