
with respect to
t
. For a connected compact Lie
group G, consider the path and loop groups on G.
The pinned Wiener measure on the loop group is
definedasthelawofaG-valued Brownian motion
starting at e and conditioned to end at e, and the heat
kernel measure is the endpoint distribution of
Brownian motion on the loop group.
It has been shown (Driver and Srimurthy 2001)
that the heat kernel measure is absolutely continuous
with respect to the pinned Wiener measure, and that
the Radon–Nikodym derivative is bounded. This
proof relies on the heat formula with a potential
[3], which is satisfied by the heat kernel measure.
They give a new proof of this heat formula. When the
group G is simply connected, Aida and Driver (2000)
prove that the heat kernel measure over a based loop
group, constructed by using the Brownian motion is
equivalent to the Brownian bridge measure over a
based loop group. When G is the circle, the Radon–
Nikodym derivative of the heat kernel measure with
respect to the pinned Wiener measure can be
calculated in terms of the Jacobi theta function
(Driver and Srimurthy 2001). On the loop space of
R
n
,attimet, the two measures, ‘‘heat kernel’’ and
‘‘pinned Wiener’’ are the same.
See also: Abelian and Nonabelian Gauge Theories Using
Differential Forms; Lie Groups: General Theory; Malliavin
Calculus; Path Integrals in Noncommutative Geometry.
Further Reading
Aida S and Driver BK (2000) Equivalence of heat kernel measure
and pinned Wiener measure on loop groups. Comptes Rendus
de l’Academie des Sciences, Paris, I 331: 709–712.
Aida, Shigeki, Elworthy, and David (1995) Differential calculus
on path and loop spaces. Logarithmic Sobolev inequalities on
path spaces. Comptes Rendus de l’Academie des Sciences Paris
Serie I Mathematics 321(1): 97–102.
Airault H and Malliavin P (1996) Integration by parts formulas
and dilatation vector fields on elliptic probability spaces.
Probability Theory and Related Fields 106: 447–494.
Bowick MJ and Rajeev SG (1987) The holomorphic geometry of
closed bosonic string theory and DiffS
1
=S
1
. Nuclear Physics B
293: 348–384.
Cruzeiro AB and Malliavin P (1996) Renormalized differential
geometry on path space: structural equation, curvature.
Journal of Functional Analysis 139: 119–181.
Driver BK (2003) Heat Kernels Measures and Infinite Dimen-
sional Analysis. Heat Kernels and Analysis on Manifolds,
Graphs, and Metric Spaces, Paris, Contemp. Math. vol. 338,
pp. 101–141. Providence, RI: American Mathematical Society.
Driver BK and Srimurthy VK (2001) Absolute continuity of heat
kernel measure with pinned Wiener measure on loop groups.
Ann. Probab. 29(2): 691–723.
Fang S (1999) Integration by parts for heat measures over loop
groups. J. Math. Pures Appl. 78(9): 877–894.
Freed DS (1988) The geometry of loop groups. Journal of
Differential Geometry 28: 223–276.
Gaveau B and Mazet E (1979) Diffusions sur des varie´te´s de
chemins. Comptes Rendus de l’Academie des Sciences, Paris
289: 643–645.
Gross L (1998) Harmonic functions on loop groups, Se´minaire
Bourbaki, vol. 1997–1998, Aste´risque No 252, Exp. No. 846,
5, 271–286.
Hsu EP (1997) Analysis on path and loop spaces. In: Hsu EP and
Varadhan SRS (eds.) IAS/Park City Mathematics Series 5.
Princeton: American Mathematical Society and Institute for
Advanced Study.
Jones V (1995) Fusion en alge`bres de von Neumann et groupes de
lacets (A. Wassermann). Se´minaire Bourbaki, vol. 1994/95.
Aste´risque No. 237 (1996), Exp. No. 800, 5, 251–273.
Levy T (2003) Yang–Mills measures on compact surfaces. Mem.
Amer Math. Soc. 166: 790.
Malliavin P (1989) Hypoellipticity in infinite dimensions. In:
Pinsky M (ed.) Diffusion Process and Related Problems in
Analysis. Chicago: Birkhauser.
Malliavin MP and Malliavin P (1992) Integration on loop groups
III. Asymptotic Peter–Weyl orthogonality. Journal of Func-
tional Analysis 108: 13–46.
Mancino ME (1999) Dilatation vector fields on the loop group.
Journal of Functional Analysis 166(1): 130–147.
Neretin Y (1994) Some remarks of quasi-invariant actions of loop
groups and the group of the diffeomorphisms of the circle.
Communication in Mathematical Physics 164: 599–626.
Norris JR (1995) Twisted sheets. Journal of Functional Analysis
132: 273–334.
Pickrell D (1987) Measures on infinite-dimensional Grassmann
manifolds. Journal of Functional Analysis 70(2): 323–356.
Metastable States
SShlosman, Universite
´
de Marseille, Marseille, France
ª 2006 Elsevier Ltd. All rights reserved.
Introduction
The theory of metastability studies the states of
the matter which ‘‘should not be there,’’ but which
still can be observed, albeit for only a short time.
One example is water, cooled below the zero
temperature. This supercool water can stay liquid,
but not for a long time, and it then freezes abruptly.
Such states are called metastable. They are not
equilibrium states; at negative temperatures the only
equilibrium state of water is ice. Physically, these
metastable states are produced from the equilibrium
states by slowly changing the external parameters,
such as the temperature (or magnetic field): one
takes, for example, water (extremely purified) at low
positive temperature, T > 0, and then lowers the
Metastable States 417