
spontaneous breaking of the particle-number sym-
metry. It is possible to describe the system in a U(1)-
invariant way, by projecting out a state of definite
particle number, a uniform superposition of all the
states in M, but it is generally less convenient to do
so.) In this case, the only nontrivial homotopy group
is
1
(M) = Z, so the only defects are linear defects
classified by a winding number n 2 Z. The defects
with n = 1 are stable vortices. Those with jnj > 1
are in general unstable and tend to break up into jnj
single-quantum vortices.
Low-temperature superc onductors also have a
U(1) symmetry, although there are important differ-
ences. This is not a global symmetry but a local,
gauge symmetry, with coupling to the electromag-
netic field. Moreover, it is not single atoms that
condense but Cooper pairs, pairs of electrons of
equal and opposite momentum and spin. These
systems too exhibit linear defects, magnetic flux
tubes carrying a magnetic flux 4nh=e.
A less trivial example is a nematic liquid crystal.
These materials are composed of rod-shaped mole-
cules that tend, at low temperatures, to line up
parallel to one another. The nematic state is
characterized by a preferred orientation, described
by a unit vector n, the director. (Note that n and n
are physically equivalent.) There is long-range
orientational order, with molecules preferentially
lining up parallel to n, but unlike a solid crystal
there is no long-range translational order – the
molecules move freely past each other as in a normal
liquid.
A convenient order parameter here is the mean
mass quadrupole tensor of a molecule. In the
nematic state, is proportional to (3nn 1); for
example, if n = (0, 0, 1), then is diagonal with
diagonal elements proportional to (1, 1, 2). In
this case, the symmetry group is SO(3) (or, more
precisely, O(3); but the inversion symmetry is not
broken, so we can restrict our attention to the
connected part of the group). The subgrou p H that
leaves this invariant is a semidirect product,
H = SO(2) n Z
2
(isomorphic to O(2)), composed of
rotations about the z-axis and rotations through
about axes in the x–y plane. (If we enlarge G to its
simply connected covering group
˜
G = SU(2), then H
becomes
˜
H = [U(1) n Z
4
]=Z
2
, where U(1) is gener-
ated as before by J
z
. The essential difference is that
the square of any of the elements in the disconnected
piece of
˜
H is not now the ident ity but the element
e
2iJ
z
= 1 2 U(1).) The manifold M of degenerate
ground states in this case is the projective space RP
2
(obtained by identifying opposite points of S
2
).
Since
˜
H has disconnected pieces, we have
1
(M) =
0
(
˜
H) = Z
2
. Thus, there can be topologically
stable linear defects, here called disclination lines,
around which the director n rotates by (see Figure 6).
The fact that these defects are classified by Z
2
rather
than Z means that a line around which n rotates by 2
is topologically trivial; indeed, n can be smoothly
rotated near the line to run parallel to it, leaving a
configuration with no defect.
There are also point defects; since
2
(M) =
1
(
˜
H) = Z, they are labeled by an integer winding
number n. In a defect with n = 1, the vector n points
radially outwards all round the defect position.
Helium-3
Finally, let us turn to helium-3, one of the most
fascinating and complex examples of spontaneous
symmetry breaking, which becomes a superfluid at a
temperature of a few millikelvin. Unlike helium-4, this
is, of course, a Fermi liquid, so it is not the atoms that
condense, but bound pairs of atoms, analogous to
Cooper pairs. In this case, however, the most attractive
channel is not the
1
S, but the
3
P, so the pairs have both
orbital and spin angular momentum, L = S = 1. There-
fore, the order parameter is not a single complex scalar
field but a 3 3 complex matrix
jk
,wherethetwo
indices label the orbital and spin angular momentum
states.
To a good approximation, the system is invar iant
under separate rotations of L and S (the effects of
the small spin–orbit coupling will be discussed
later), so the symmetry group is
G ¼ Uð1Þ
Y
SOð 3Þ
L
SOð3Þ
S
½12
where the subscripts denote the generators and U(1)
Y
represents multiplication by an overall phase factor,
e
iY
:
jk
7!
jk
e
i
. This complicated symmetry allows
much scope for a large variety of defects. There are, in
fact, two distinct superfluid phases, A and B,with
different symmetries (and indeed in the presence of a
magnetic field there is a third, A1).
In the
3
He-A phase, the order parameter has the
form
jk
/ (m
j
þ in
j
)d
k
, where m, n, d are unit
vectors, with m ? n; if we set l = m ^ n, then
Figure 6 Orientation of molecules around a disclination line.
262 Topological Defects and Their Homotopy Classification