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240 Smart Packaging Technologies for Fast Moving Consumer Goods
development, uses the exothermic reaction between anhydrous calcium chloride and water.
When the substances are mixed, heat swirls around the aluminium cup and is conducted into
the beverage. The consumer shakes the container for 40 seconds before peeling off the lid
and a temperature rise of around 23
◦
C is achieved. This beverage is a niche market product
sold across Europe in sports venues, motorway rest areas and many other outlets. Hot drink
variants are coffee, cappuccino, chocolate, coffee with grappa, and tea with lemon.
When it comes to food, spin-off technology from the military MRE programmes using
highly reactive exothermic reactions based on magnesium oxidation or the reaction between
potassium permanganate and glycerine has created a niche but growing market for self-
heating food products for emergency services and the outdoors sector.
The increasingly convenience-orientated domestic market requires a means to heat all
types of food and beverages including high viscosity liquids and solid products, i.e. thick
soups, snacks including wraps, fajitas, stuffed pitta bread, ready meals, pasta, rice and
stews. To date, the technologies for self-heating have been confined to lime/water reactions,
where heat output is lower but the reaction is safer. Heating times can be long for solid
food products since heat is transferred from the heating source to the product purely by
conduction.
By ensuring that excess water is present with the lime/water reaction, a new heat transfer
process is being developed by Thermotic Developments – that of direct steam heating. This
highly efficient system transfers heat to the product by injecting steam directly into and
through the food. Steam is a very effective medium for transferring energy with 1 g steam
theoretically possessing 2 kJ of energy.
13.5.2 Self-Cooling Technologies
Notions of self-chilling packaging continue to excite investors and marketers alike, and the
brief sounds easy. ‘Design a self-cooling device for beverages such as colas, beer and fruit
juice of 330 and 500 millilitre capacity that will decrease the temperature from the existing
value to around 4
◦
C in a convenient (say 3 minute) time period. Do this at a moderate on-
cost and without compromising existing environmental considerations, safety, portability
or recycling and untold riches will be yours’.
Technology choices in practice boil down to two – endothermic chemical reactions and
heat pump technology using water vapour as the heat transfer fluid. Forms of gaseous high
pressure expansion can provide effective and rapid cooling but can quickly be ruled out on
environmental and safety grounds.
Endothermic reactions tend to be weak but this has not stopped the commercialisation
in Italy of self-cooling coffee – ‘Freddo Freddo’ which employs the endothermic reaction
between sodium thiosulfate pentahydrate and water. By contrast water evaporation can be
a powerful cooling process, as stepping out of the shower on a cold day demonstrates. The
evaporation of 10 ml of water can theoretically cool 330 ml of water by 18
◦
C.
For single serve containers, the technically viable heat pump technology has not yet
become commercial. High cost and lack of reliability appear to be the key factors, but
the technology is finding commercial success in party keg sizes of beer. The German CS-
Metallbau Company has developed the world’s first self-chilling refillable keg using zeolite
heat pump technology. The technology is licensed to Cool-System Bev. GmbH and is being