
503
METHODS
OF
SOLUTION
equation:
(12.70)
Here
E
is the energy of the electron and
m
is its mass. If we define the constant
k2
=
2mE/h2, Equation 12.70 can
be
rewritten as
2m
h2
(V2
+
k2)
+(F)
=
-V(F)+(i-).
(12.71)
This last equation is a linear differential equation with
+(I;)
as the dependent variable.
A
Green's function approach to solving
this
equation gives the result
(1
2.72)
The first term on the
RHS
is the solution for
+(F)
when
V(F)
is zero, the homogeneous
version of Equation 12.71. The second term is
an
integral over all space involving
the Green's function
g(F1i').
The Green's function itself is a solution to
(V2
+
k2)
g(FIF')
=
S3(F
-
P).
(12.73)
It will be assumed that the Green's function vanishes at infinity. Applying this bound-
ary
condition gives
(12.74)
If
$(F)
were not sitting inside the Green's function integral of Equation 12.72, we
would already have our desired solution. But since it does appear both inside and
outside of the integral, we resort to the Neumann series method described earlier. The
potential
V(F)
is assumed to be a small perturbation to the problem. The zero-order
solution is just the wave function for a free electron
+o(f)
=
eik.r
(12.75)
We obtain the first-order solution by forcing this solution back into Equation 12.72:
(12.76)
This solution is referred to as the first
Born
approximation. Higher-order approxirna-
tions follow the Neumann series solution method.
You may have noticed something a little odd about
this
example. In the derivation
of the Neumann series, the constant
A
needed to be small enough for the series
to converge. In this example, however, the constant
A
is nowhere
to
be seen. The
convergence of this solution is controlled by the magnitude of
V(i-).