6.2 Diffusion of Electromagnetic Fields 355
perpetuum mobile of the second kind). It is this second law that does not entirely
prohibit the described process, but declares it as very improbable, so that one can
not expect to actually witness it. The basis of this are probability evaluations of
micro states. In our specific case, it is very improbable that the charges in a
conductor, by pure chance, move in such a way that a macroscopic current results
(by chance shall mean that the motion is not caused by an external field). Much
more likely is that the charges move disorderly with different velocities in all
possible directions, mutually cancelling each other in a spatial and temporal
average. Nevertheless, taking sufficiently accurate measurements (with sufficient
spatial and temporal resolution), will reveal small, fluctuating currents, which are
responsible for the permanent background noise of the macroscopic events. The
problems arising from noise are not only theoretically interesting but also of great
practical importance (for example, because they define the limits of accuracy for
very exact measurements), but this is not the topic of this text. Here, we merely
want to note that the processes described in eqs. (6.27) through (6.30) are
macroscopically irreversible. This irreversibility is formally expressed by the
simple time derivative. Replacing t by -t changes the equation, it is – as it is known
– not invariant against time reversal. In other words, there is a difference whether
time increases or decreases. Therefore, the process can not just run backwards.
The wave equation, which covers electromagnetic waves, will be discussed in
Chapter. 7. Its form for E is
.
(6.31)
The only significant difference to eq. (6.27) is that it contains the second time
derivative. This makes it invariant against time reversal. As we will see, it
describes processes (waves), which may proceed both forward and backward in
time.
To envision the difference, one might imagine taking a movie of such
irreversible processes (for example diffusion) or reversible processes (for example
waves). Then play those movies backwards. In case of a wave (more precisely: not
attenuated wave, i.e., one that does not irreversibly loose energy) the movie played
backwards describes the same natural situation as the one played forward. On the
other hand, the movie of the irreversible process played backwards would seem
unnatural and very puzzling.
Another remark on the formality of the underlaying mathematics shall be
made: One distinguishes three types of partial differential equations of second
order. They are called elliptic, parabolic, and hyperbolic. All three types are very
important in science, and the formal differences also manifest themselves in
practical significance. That is, these three types of equations describe three
significantly different phenomena. When just considering two independent
variables (x, y or x, t), then the equation
(6.32)
∇
2
E µε
∂
2
E
∂t
2
----------
=
∂
2
ϕ
∂x
2
---------
∂
2
ϕ
∂y
2
---------+
ρ
ε
0
-----–=