
ELECTRON EMISSION
All electron tubes“ depend for their operation on the
flow of electrons within the tube, through either high
vacuum or
an
ionized gas. The electrons are emitted
from a cathode surface as a result of one of four pro-
cesses that are distinguished on the basis of
the
mecha-
nism by which the electrons are enabled to leave the
surface. These processes are elevated temperature
(thermionic or primary emission); bombardment by
other particles, generally electrons (secondary emis-
sion); the action of a high electric field (field emis-
sion); or the incidence of photons (photoemission).
Therm
ionic
Em
ission
Thermionic emission originates from the thermally
excited electrons that have sufficient kinetic energy to
overcome the vacuum barrier. The sum of all these ther-
mal electrons gives rise to the Richardson-Dushman
equation, which
is
J
AT^
exp(-+/kT) (Eq.
1)
where
J
is emission density in amperes/cm2,
A
is 120 amperes/cm2,
+
is work function in electron volts (eV),
T
is temperature in kelvins
(K),
and
k,
the Boltzmann constant, is 8.6164
x
lob5
eV
K-l.
Emission density is
an
exponential function of the
work function. Between
1000
K
and 2000
K,
a
decrease in the work function of 0.2 to 0.4 eV causes
an
order of magnitude increase in the emission density.
The work function of commonly used thermionic cath-
odes varies from 4.6 eV (tungsten) to 1.5 eV (oxide-
coated cathodes).
The first thermionic cathodes used in quantity were
made from pure tungsten
(W).
Because
of
the high
work function, a very high temperature is required to
provide a reasonable emission density. For example,
Eq.
1
indicates that an emission density of
0.3
A/cm2
requires a temperature of 2150°C (or 2423
K).
To reduce the operating temperature, thoria (tho-
rium oxide) was mixed with
W.
Thorium would diffuse
to the surface of
W
and lower the work function. The
cathode surface was sometimes carburized to reduce
the thorium evaporation, extending the operating life.
The resulting surface has
a
work function of
-
3.2
eV.?
For comparison with pure tungsten, the emission den-
*
J.
W.
Gewartowski
and
H.
A.
Watson,
Principles
Of
Electron Tubes
(Princeton, NJ: Van Nostrand, 1965).
K.
R.
Spangenberg,
Vacuum Tubes
(New York: McGraw-Hill
Book
Co., 1948).
A.
H.
W. Beck,
Thermionic Valves, Their Theory
and Design
(London:
Cambridge University
Press,
1953).
Standards on Electron Tubes: Definitions
of
Terms
(New
York:
Institute
of
Radio Engineers, 1950).
t
Reference
1.
sity of 0.3 A/ cm2 requires 1950°C (2223
K),
a 200°C
reduction in temperature.
A
significant reduction in work function was real-
ized
in
oxide-coated cathodes. The oxide-coated cath-
odes consist of an alkaline-earth-oxide coating on a
metal substrate, which is usually nickel (Ni). A stan-
dard ASTM (American Society for Testing and Materi-
als) mixture of the oxide coating is 49? 44, and
7
atomic percent of Ba, Sr, and Ca oxide, respectively.
The substrate can be made of either active or passive
Ni, depending on whether or not it contains reducing
agents. A typical active Ni contains 4%
W
in the bulk.
The work function of a fully activated oxide-coated
cathode is 1.85 eV and
1.5
eV on passive and active Ni
substrates, respectively.$
The initial alkaline earths are
in
carbonate form and
mixed by an organic binder. The carbonates and binder
are either sprayed onto the substrate or they are cut and
transferred from a self-supporting sheet, which is
known as a “Sarong” coating. Activation of an oxide-
coated cathode requires several hours of outgassing. A
copious quantity of hydrocarbon gases is released ini-
tially from the decomposition of the organic binder,
and then a large amount of CO, is released from the
decomposition of the carbonates into the respective
oxides.
It
is advisable to raise the cathode temperature
gradually during the carbonate conversion to avoid
CO, overpressure, which could cause melting of the
oxide coating. On some oxide-coated cathodes, high
work function patches were observed
to
form, which
were identified as the formation of CaO slags on the
surface caused by BaO/BaCO, eutectic melting during
the conversion process.§
The activation and poisoning processes of an oxide-
coated cathode are explained by a semiconductor
model.” The oxygen vacancies in the oxide lattice act
as electron donors. During activation, the reducing
agents, such as
W
in the Ni substrate, react and bind
with the oxygen atoms in the oxides and generate oxy-
gen vacancies. The creation of these donors shifts the
Fermi level up from
the
intrinsic mid-band gap to near
the bottom of the conduction band, and consequently,
the work function is lowered. Thermal excitation lifts
some of the electrons
in
the donors to the conduction
band, and the mobile electrons are needed in the elec-
tron emission process. Cathode poisoning by oxidizing
gases such as
0,,
H,O,
and CO, occurs through filling
the oxygen vacancies and shifting the Fermi level back
toward
the
mid-band gap. Sulfur, which is present on
the surface of many metals, can have a detrimental
effect on the oxide-coated cathodes since
S
can
also
fill the oxygen vacancies. The well-known 10-volt
slump occurs when
S
is transferred from the metal
grids
to
the oxide coating through electron-stimulated
$
Reference
2.
§
Reference
3.
‘I
Reference
4.