multilayer structures. A suitable multilayer structure
used to pre-package foods must have sufficient flexibility,
resilience, and resistance to delamination during the
compression process, because a loss of packaging integrity
would result in major food safety and quality deterioration
(5). Initially, the innermost layer of the structure should
be selected to limit food–package interactions (unless the
substance exchange is desired and beneficial; see Active
Packaging) and to provide hermetic a seal. Heat-sealable
materials such as polyolefins could be a good option,
although other sealing process can widen the materials
spectra (see the sealing section). The outermost layer of
the structure should resist the action of the pressurizing
fluid. With the exception of highly hydrophilic materials
such as polyvinyl alcohol, most polymeric materials could
be suitable. Reversed printed oriented polypropylene,
polyester, or polyamide films can be good choices.
Finally, the barrier properties to oxygen can be tailored
to the product requirement by varying the materials and
the number of layers in the structure (see the barrier
section). Many structures have been tested using PA,
EVOH, PVOH, aluminum foil, or polymer films coated
with aluminum, silicon oxide (SiOx), or aluminum oxide
(AlOx). Most of these packaging structures have been
tested with no relevant changes caused by the HPP
treatment. The packages showed sufficient degree of flex-
ibility and resilience to compensate for the reduction in
volume, no significant changes in tensile strength being
observed between controls and HPP treated samples.
Heat seal strength is a critical point in packages,
because if any void is present or generated by the treat-
ment along the seal of the package, the safety of the
packaged food will be seriously compromised. In general,
thermoplastic materials have been proven to withstand
HPP without significant losses in sealability. In other
technologies, such as in retortable food packages, the
seal is exposed to high temperatures and pressure
changes in both directions, which can affect and even
break the sealing. However, the sealing is not exposed to
such critical conditions in HPP treatment, since the
package always receives the pressure from the outside
and the temperature rarely reaches 701C.
High-pressure-induced delamination has been ob-
served in flexible packages made of composite materials
and having relatively large headspace volumes. Gases
reduce their volume during the HPP treatment much
more than food and packaging materials, promoting ten-
sions and failures. Headspace volumes should be mini-
mized to reduce the chances of having seal damages,
delaminations, and large deformations. The presence of
large headspace volumes increases largely the time to
obtain the required pressure since more pressurizing fluid
has to be pumped in the vessel. Also the packaging design
with materials of diverse nature can produce changes
in packaging properties. Thus, aluminum and metal oxi-
des present lower compressibilities than do polymeric
materials. This difference can be responsible for
the delamination and blistering observed in barrier
structures containing aluminum layer or coatings which
increase in delamination with exposure time and tem-
perature (5, 6).
BARRIER PROPERTIES
The barrier properties are often the most relevant char-
acteristic to be considered in the design of functional
polymeric packages for food. Therefore, HPP-induced
barrier changes can have a very negative impact concern-
ing packaged food quality. In general, the permeability to
oxygen, carbon dioxide, and water vapor do not change
relevantly after the HPP treatment. Nevertheless, a large
decrease of barrier has been observed in metalized films
apparently due to the damage caused in the aluminum
layer (4). It is also relevant to mention that HPP treat-
ments produce much less damage than do conventional
thermal treatments in the barrier properties of hydrophi-
lic materials such as EVOH. The concurrence of low
temperatures of treatment, shorter treatment period,
and the presence of high pressure produces a much lower
water sorption in those polymers, which results in the
reduction of package plasticization and of the subsequent
loss of barrier. The volume reduction of the voids present
in the polymer (free volume) which takes place during the
high-pressure treatment could be responsible for a de-
crease in solubility and a much slower molecular diffusion
though the polymer matrix. These two parameters con-
tribute to reduce the extent of mass transport through
packages and food–package interactions. In agreement
with this statement, migration studies showed that HPP
treatment do not alter the migration values of flexible
packaging structures (7).
Tests should be carried out to confirm the validity of a
package for HPP treatments keeping in mind that,
although most polymeric materials are suitable since their
main properties are not modified, good sealing properties,
design of the package structure with materials of similar
compressibility, and the reduction of the package head-
space volume will lead to a successful packaging solution.
BIBLIOGRAPHY
1. E. Palou, A. Lo
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2. J. A. Torres and G. Velazquez, ‘‘Hydrostatic Pressure Proces-
sing of Foods’’ in S. Jun and J. Irudayaraj, eds., Food Proces-
sing Operations Modeling: Design and Analysis, CRC Press,
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Barrier Laminated Films,’’ Packag. Technol. Sci. 13, 183–195
(2000).
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1103 (2003).
900 PACKAGING OF FOOD FOR HIGH PRESSURE TREATMENTS