
other hand, there exist examples of field theories where
perturbative methods fail but that nevertheless can be
quantized. This suggests that the consideration of
nonperturbative techniques in the quantization of the
gravitational field could be a promising avenue.
In particular, canonical quantization methods
appear attractive for attempting a nonperturbative
quantization of gravity. Canonical methods force
the introduction, in a clear way, of a Hilbert space
of states and definition of the quantum operators of
interest. The application of canonical methods to
classical general relativity was pioneered by Dirac
and Bergmann in the late 1950s. During the 1960s,
the resulting canonical theories were considered in a
quantum setting by DeWitt. At the time it appeared
that making progress in the canonical quantization
of general relativity was going to be quite a
challenge. In particular, the canonical theory has
constraints, which have to be implemented as
operator identities quantum mechanically. The
wave functions were functionals of the spatial metric
of spacetime. One of the operator identities to
be satisfied implies that the wave functions only
depend on properties of the spatial metric that
are invariant under spatial diffeomorphisms. This
is a direct consequence of general relativity being
a theory that is independent of coordinate choice
since a diffeomorphism changes the assignment of
coordinates to points in the manifold. Finding such
wave functions already presented a challenge, since
there is no well-grounded mathematical theory of
functionals of diffeomorphism-invariant classes of
metrics. Moreover, the other operator identity to be
imposed, known as the Hamiltonian constraint or
Wheeler–DeWitt equation, was a nonpolynomial
complicated operator equation that does not admit
a simple geometrical interpretation and needs to be
regularized. Since one does not have a background
metric to rely upon, traditional regularization
techniques of quantum field theory are not suitable
to deal with the Hamiltonian constraint.
These difficulties severely hampered development
of canonical methods for the quantization of general
relativity for approximately two decades. The
situation started to change when Ashtekar noticed
that one could choose a different set of variables
to describe general relativity canonically. Instead of
using as variable the spatial metric q
ab
, Ashtekar
chooses to use a set of (densitized) frame fields
~
E
a
i
.
The relationship between the metric and the
densitized frames is det (q
ab
)q
ab
=
~
E
a
i
~
E
b
i
and we are
assuming the Einstein summation convention, that
is, the index i is summed from 1 to 3 (such an index
labels which vector in the triad one is referring to).
The resulting theory has an additional symmetry
with respect to usual general relativity, in the sense
that it is invariant under the choice of frame. This
symmetry operates on the index i as if it were
an SO(3) symmetry. As canonical momenta the
usual choice is to pick the extrinsic curvature of the
3-geometry. Ashtekar chooses a variable related to it
that behaves under frame transformations as an
SO(3) connection, A
i
a
. The resulting theory is there-
fore cast in terms of a canonical pair (
~
E
a
i
, A
i
a
), with i
an SO(3) index. One can therefore consider the
canonical pair as that of a Yang–Mills theory
associated with the SO(3) group. In fact, associated
with the extra symmetry under triad rotations the
theory has a new set of constraints that take
the form of a Gauss law, D
a
~
E
a
i
= 0 with D
a
the
covariant derivative formed with the connection A
i
a
.
This allows us to view the phase space of a Yang–
Mills theory as the kinematical arena on which to
discuss quantum gravity. The theory is of course
different from the Yang–Mills theory. In particular,
it still has constraints that imply that it is invariant
under spacetime diffeomorphisms. In the canonical
picture, these constraints appear asymmetrically as
one constraint is associated with time evolution
(‘‘Hamiltonian con straint’’) and a set of three
constraints is associated with spatial diffeomorph-
isms (‘‘diffeomorphism constraint’’).
If one quantizes the theory starting from the
Ashtekar formulation, given the resemblance with
Yang–Mills theory, the natural choice for a represen-
tation of the quantum wave functions is to consider
wave functions of the connection [A]thatare
invariant under SO(3) transformations. Such a repre-
sentation is known as ‘‘connection representation.’’
There is significant experience in Yang–Mills theory in
constructing such wave functions. In particular, it is
known that if one considers the parallel transport
operator defined by a connection around a closed
curve (holonomy) and one takes its trace (‘‘Wilson
loop’’), the resulting object is invariant under SO(3)
transformations. What is more important, the set of
traces of holonomies along all possible closed loops is
an overcomplete basis for all gauge-invariant func-
tions. More recently, it has been shown that one can
construct a less redundant complete basis using
techniques from spin networks. We will discuss later
on how to do this.
Since any gauge-invariant functional can be
expanded in the basis of Wilson loops, one can
choose to represent it through the coefficie nts of
such an expansion. These coefficients are functions
of the curve upon which the corresponding element
of the basis of Wilson loops is based. The
representation of wave functions in terms of such
coefficients is called ‘‘loop representation.’’ Wave
216 Knot Invariants and Quantum Gravity