
638
INTRODUCTION
TO
GROUP
THEORY
(b)
Show that the vectors formed by the character values of the irreducible
representations are
all
orthogonal to each other, but not
to
the vector formed
by the character values of the
Diw
representation.
(c)
Determine how many times each of the irreducible representations appears
in the decomposition of the
Din
representation.
12.
Consider the symmetry group associated with a diatomic molecule.
This
molecule
has
two identical atoms located
in
the xy-plane, as shown below:
(a)
Determine the
four
elements of the symmetry group, which correspond to
(a)
Construct a
2
X
2
matrix representation
of
this
group by associating a trans-
(e)
Determine the multiplication table of
this
group.
(d)
Find the transformation that simultaneously diagonalizes all the elements
of
the representation found for part (b) and list all the diagonalized matrix
elements.
(e)
The transformation you found in part (d) can be viewed
as
a coordinate sys-
tem transformation. Sketch the locations
of
the atoms in
this
new coordinate
system.
rigid rotations in the plane and reflections.
formation matrix with each element.
13.
In Equation
15.68,
we derived a matrix representation for the
g2
element of
D3.
Derive the other elements of
this
representation, which are listed in Table
15.30.
14.
Another way to write the general form
of
the continuous
SU(2)
group is
eia
cos
y
(15.89)
where
a,
p,
and
y
are
all
real quantities. Show that
this
form
automatically
satisfies both the unimodular and unitary conditions.
cosy
1
'
eiP
sin
y
-e-iP
e-ia
[