
Chapter 1
Energy
Dispersion
Relations
in
Solids
The transport properties
of
solids are closely related to the energy
dispersion relations
E
(k)
in
these materials and
in
particular to the behavior
of
E
(k)
near
the
Fermi level. Conversely, the analysis
of
transport
measurements provides a great deal
of
information on E
(k).
Although
transport measurements donot generally provide the most sensitive tool for
studying
E
(k),
such measurements are fundamental to solid sthte physics
because they can be carried out on nearly all materials and therefore provide
a valuable tool for char-acterizing materials. To provide the necessary
background for the discussion
of
transport properties, we give here a brief
review
of
the energy dispersion relations E
(k)
in solids.
In
this connection,
the two limiting cases
of
weak and tight binding.
ONE
ELECTRON E
(k)
IN
SOLIDS
In the weak binding approximation, we assume that the periodic potential
V
(r)
= V
(r
+
~)
is
sufficiently weak so that the electrons behave almost as
if
they were free and the effect
of
the periodic potential can be handled in
perturbation theory.
In
this formulation V
(r)
can be an arbitrary periodic
potential. The weak binding approximation has achieved some success
in
describing the valence electrons
in
metals. For the core elec-trons, however,
the potential energy
is
comparable with the kinetic energy
so
that core electrons
are tightly bound and the weak binding approximation is not applicable. In
the weak binding approximation we solve the SchrAodinger equation
in
the
limit
of
a very weak periodic potential
HiJ,.'
=
E1\!.
Using time {independent perturbation theory we write
E(k)
= EO(k) + E(I)
(k)
+
E(2)(k)
+ ...
and take the unperturbed solution
to
correspond to V
(r)
= 0
so
that
E(O)
(k)