growing cracks. For these cracks to initiate, the PE material must have
a crystalline structure. The more crystalline the structure, the easier
it is for the cracks to initiate. The transition from the ductile to the
brittlelike state results in not only lower longer-term strain capacity,
but also lower longer-term strength and less endurance to cyclic
stressing.
For nonpressure pipes, it is possible for cracks to form and grow to
such extent as to eventually compromise the infiltration and exfiltra-
tion requirements on the pipe and may also destroy the structural
integrity of the pipe-soil system. The possibility of the development
and continued growth of cracks in a pressure pipe is usually unac-
ceptable, particularly when the pipe is carrying a dangerous material
such as natural gas.
PE materials used to manufacture pipes must offer adequately high
resistance to crack initiation and propagation. PE polymer materials
are partially crystalline and partially amorphous. Density and molec-
ular weight have tremendous influence on properties of the particular
polyethylene. The reader should understand that high molecular
weight and high density are not the same thing, nor are they always
mutually beneficial. Higher-density polyethylene materials are more
crystalline in structure, which results in higher stiffness, tensile
strength, and hardness. Increases in these properties are often consid-
ered beneficial. However, these benefits are accompanied by decreases
in toughness, impact strength at lower temperatures, and long-term
crack resistance. One may somewhat compensate for these losses by
increasing the molecular weight of the PE. The downside of increasing
the molecular weight is a simultaneous increase in the melt viscosity.
Manufacturers of pipe are concerned because high melt viscosities
mean the ease of processability is diminished, and it becomes more dif-
ficult to manufacture pipe. The challenge is to balance density and
molecular weight to offer long-term ductility, and resistance to stress
cracking, and still be able to process the material into a pipe.
To meet this challenge, resin suppliers have copolymerized ethylene
with small amounts of other monomers. Extreme care must be taken
by polymer chemists because experience has shown that such copoly-
mers can become more crystalline with time. The rate in the process in
moving away from an amorphous structure to a crystalline structure
is a function of temperature. This is more of a concern for commercially
available PE polymers (compared to simple homopolymers such as
PVC) because of the greater diversity in the molecular structure. For
PVC, it is possible to fairly precisely link basic polymer characteristics
such as density, molecular weight, and melt viscosity with resultant
mechanical properties, such as strain capacity and long-term strength.
466 Chapter Seven